聚乳酸纳米复合材料流变性能研究进展

doi:10.19491/j.issn.1001-9278.2020.09.018

中国塑料 ›› 2020, Vol. 34 ›› Issue (9): 103-110.DOI: 10.19491/j.issn.1001-9278.2020.09.018

• 综述 • 上一篇

聚乳酸纳米复合材料流变性能研究进展

罗静云¹^,², 白世建¹^,², 张玉霞¹^,²(), 周洪福¹^,²

^1.北京工商大学化学与材料工程学院，北京 100048
^2.塑料卫生与安全质量评价技术北京市重点实验室，北京 100048

收稿日期:2020-07-03 出版日期:2020-09-26 发布日期:2020-09-25
基金资助:
北京工商大学2020年研究生科研能力提升项目

Research Progress in Rheological Behavior of Poly(lactic acid) Nanocomposites

Jingyun LUO¹^,², Shijian BAI¹^,², Yuxia ZHANG¹^,²(), Hongfu ZHOU¹^,²

^1.College of Chemistry and Materials Engineering of Beijing Technology and Business University, Beijing 100048, China
^2.Beijing Key Laboratory of Quality Evaluation Technology for Hygiene and Safety of Plastics, Beijing 100048, China

Received:2020-07-03 Online:2020-09-26 Published:2020-09-25
Contact: Yuxia ZHANG E-mail:zhangyux@th.btbu.edu.cn

摘要/Abstract

摘要：

综述了各种纳米粒子，包括生物质基纳米粒子、碳基纳米粒子、纳米黏土等对聚乳酸(PLA)在剪切力场作用下的流变性能影响及其各自含量、表面处理和与PLA基体之间相互作用等对其流变性能的影响，并总结了纳米粒子对PLA流变性能的作用机理。

关键词: 聚乳酸, 纳米粒子, 复合材料, 流变性能

Abstract:

This paper reviewed the research progress in the effect of nanoparticle type on the rheological behavior of poly(lactic acid) (PLA)?based composites under a shear force. These nanoparticles include biological fillers, carbon?based fillers and nano clay. The paper also introduced the effects of filler content, surface treatment and particle?matrix interaction on the rheological behavior of the composites. Moreover, the relevant mechanisms were further discussed.

Key words: poly(lactic acid), nanoparticles, composite, rheological behavior

中图分类号:

TQ321

罗静云, 白世建, 张玉霞, 周洪福. 聚乳酸纳米复合材料流变性能研究进展[J]. 中国塑料, 2020, 34(9): 103-110.

Jingyun LUO, Shijian BAI, Yuxia ZHANG, Hongfu ZHOU. Research Progress in Rheological Behavior of Poly(lactic acid) Nanocomposites[J]. China Plastics, 2020, 34(9): 103-110.

图/表 7

图1 PLA/CNC纳米晶复合材料储能模量与CNC含量的关系[11]

Fig. 1 Storage modulus of PLA/CNC nanocomposites as a function of CNC loading[11]

图2 纯PLA和不同含量CNC的PLA/CNC复合材料的储能模量和复数黏度[24]

Fig. 2 Storage modulus and complex viscosity of neat PLA and its nanocomposites with various loading of CNC[24]

图3 纯PLA及其纳米复合材料的动态流变性能[25]

Fig.3 Dynamic rheology of neat PLA and its nanocomposites[25]

图4 CNT含量为0.02 %时复合材料的TEM照片[29]

Fig. 4 TEM image of PLA/CNT composites with a CNT content of 0.02 %[29]

图5 PLA/GNPs纳米复合材料的储能模量和损耗模量[33]

Fig. 5 Storage modulus and loss modulus of PLA/GNPs nanocomposites[33]

图6 PLA/GNPs纳米复合材料的SEM照片[33]

Fig.6 SEM imges of PLA/GNPs nanocomposites with various loading of GNPs[33]

图7 不同PLA/OMLS复合材料的储能模量、损耗模量、复数黏度和流动活化能[37]

Fig.7 Storage modulus，loss modulus，complex viscosity and Ea of PLA/OMLS nanocomposites[37]

参考文献 42

1	DIN M I, GHAFFAR T, NAJEEB J, et al. Potential Perspectives of Biodegradable Plastics for Food Packaging Application Review of Properties and Recent Developments [J]. Food Additives & Contaminants: Part A, 2020, 37 (4):665⁃680.
2	ZARE Y. Recent Progress on Preparation and Properties of Nanocomposites from Recycled Polymers: A Review [J]. Waste Management, 2013, 33 (3):598⁃604.
3	陈卫丰, 居学成, 翟茂林. 完全生物降解聚乳酸共混复合材料的研究进展[J]. 高分子材料科学与工程, 2011, 27(2):171⁃174.
	CHEN W F, JU X C, ZHAI M L. Research Progress in Completely Biodegradable Poly(lactic acid) Blends [J]. Polymer Materials Science and Engineering, 2011, 27(2):171⁃174.
4	MENG X, SHI G T, CHEN W J, et al. Structure Effect of Phosphite on the Chain Extension in PLA [J]. Polymer Degradation and Stability, 2015, 120:283⁃289.
5	JAVID R. Synthesis of Polystyrene⁃Poly lactide Bottlebrush Block Copolymers and Their Melt Self assembly into Large Domain Nanostructures[J].Macromolecules, 2009, 42 (6):2 135⁃2 141.
6	YANG S l, WU Z H, YANG W, et al. Thermal and Mechanical Properties of Chemical Crosslinked Poly (lactic acid) [J]. Polymer Testing, 2008, 27 (8):957⁃963.
7	ROSTAMI A, VAHDATI M, NAZOCKDAST H, et al. Rheology Provides Insight into Flow Induced Nanostructural Breakdown and its Recovery Effect on Crystallization of Single and Hybridcarbon Nanofiller Filled Poly (lactic acid) [J]. Polymer, 2018, 134:143⁃154.
8	WANG X Z, LI Y, JIAO Y, et al. Microcellular Foaming Behaviors of Poly (lactic acid)/Low⁃Density Polyethylene Blends Induced by Compatibilization Effect [J]. Journal of Polymers and the Environment, 2019, 27 (8):1 721⁃1 734.
9	ROGHANI⁃MAMAQANI H, HADDADI⁃ASL V, SALAMI⁃KALAJAHI M. In Situ Controlled Radical Polymerization: A Review on Synthesis of Well⁃defined Nanocomposites [J]. Polymer Reviews, 2012, 52 (2):142⁃188.
10	CAPUANO G, FILIPPONE G, ROMEO G, et al. Universal Features of the Melt Elasticity of Interacting Polymer Nanocomposites [J]. Langmuir, 2012, 28 (12):5 458⁃5 463.
11	BAGHERIASL D, CARREAU P J, RIEDL B, et al. Shear Rheology of Poly Lactide (PLA)⁃Cellulose Nanocrystal (CNC) Nanocomposites [J]. Cellulose, 2016, 23 (3):1 885⁃1 897.
12	NORAZLINA H, KAMAL Y. Graphene Modifications in Poly lactic acid Nanocomposites: A Review [J]. Polymer Bulletin, 2015, 72 (4):931⁃961.
13	XU C J, CHEN J X, WU D F, et al. Poly lactide/Acetylated Nanocrystalline Cellulose Composites Prepared by A Continuous Route: A Phase Interface⁃Property Relation Study [J]. Carbohydrate Polymers, 2016, 146:58⁃66.
14	GUPTA A, SIMMONS W, SCHUENEMAN G.T, et al, Rheological and Thermo⁃Mechanical Properties of Poly (lactic acid)/Lignin⁃Coated Cellulose Nanocrystal Composites [J]. ACS Sustainable Chemistry & Engineering, 2017, 5 (2):1 711⁃1 720.
15	REN J X, SILVA A S, RAMANAN K, et al. Linear Viscoelasticity of Disordered Polystyrene⁃Polyisoprene Block Copolymer Based Layered⁃Silicate Nanocomposites [J]. Macromolecules, 2000, 33 (10):3 739⁃3 746.
16	KRISHNAMOORTI R, BANIK I, XU L. Rheology and Processing of Polymer Nanocomposites [J]. Reviews In Chemical Engineering, 2010, 26:3⁃12.
17	GALGALI G, RAMESH C, LELE A. A Rheological Study on the Kinetics of Hybrid Formation in Polypropylene Nanocomposites[J].Macromolecules, 2001, 34 (4):852⁃858.
18	卢红斌,杨玉良. 填充聚合物的熔体流变学[J]. 高分子通报, 2001, 16: 18⁃26.
	LU H B, YANG Y L. Advances in the Rheology of Filled Polymer Melts [J]. Polymer Bulletin, 2001, 16:18⁃26.
19	KOURKI H, MORTEZAEI M. Prediction of the Viscoelastic Response of Filler Network in Highly Nanofilled Polymer Composites [J]. Journal of Composite Materials, 2015, 49 (30):3 799⁃3 807.
20	FRÖHLICH J, NIEDERMEIER W, LUGINSLAND H D. The Effect of Filler⁃Filler and Filler⁃Elastomer Interaction on Rubber Reinforcement [J]. Composites Part A: Applied Science and Manufacturing, 2005, 36:449⁃460.
21	KOURKI H. Particle Sedimentation: Effect of Polymer Concentration on Particle–Particle Interaction [J]. Powder Technology, 2012, 221:137⁃143.
22	罗成成, 王晖, 陈勇. 纤维素的改性及应用研究进展[J]. 化工进展, 2015, 34 (3):767⁃773.
	LUO C C, WANG H, CHEN Y. Progress in Modification of Cellulose and Application [J]. Chemical Industry and Engineering Progress, 2015, 34 (3):767⁃773.
23	MALMIR S, MONTERO B, RICO M, et al. Morpho⁃logy Thermal and Barrier Properties of Biodegradable Films of Poly (3⁃hydroxybutyrate⁃co⁃3⁃hydroxyvalerate) Containing Cellulose Nanocrystals [J]. Composites Part A: Applied Science and Manufacturing, 2017, 93:41⁃48.
24	ZHANG Y C, CUI L, XU H, et al. Poly (lactic acid)/Cellulose Nanocrystal Composites via the Pickering Emulsion Approach: Rheological,Thermal and Mechanical Properties [J]. International Journal of Biological Macromolecules, 2019, 137:197⁃204.
25	WEI L Q, LUO S P, MCDONALD A G, et al. Preparation and Characterization of the Nanocomposites from Chemically Modified Nanocellulose and Poly (lactic acid) [J]. Journal of Renewable Materials, 2017, 5 (5):410⁃422.
26	ABDALLAH W, MIRZADEH A, TAN V, et al. Influence of Nanoparticle Pretreatment on Thethermal Rheological and Mechanical Properties of PLA⁃PBSA Nanocomposites Incorporating Cellulose Nanocrystals or Montmorillonite [J]. Nanomaterials, 2018, 29 (1):20⁃24.
27	吴长庆, 林祥, 任冬云,等. 高填充性聚合物/纳米粒子复合材料的流变行为研究进展[J]. 中国塑料, 2018, 32 (2):1⁃9.
	WU C Q, LIN X, REN D Y, et al. Research Progress in Rheological Behaviors of Ighly Hilled Polymers Based Nanocomposites [J]. China Plastics, 2018, 32 (2):1⁃9.
28	王劭妤, 石坚, 郑来云. 碳纳米管/PLA复合材料制备及性能[J]. 复合材料学报, 2012, 29 (6): 50⁃54.
	WANG S Y, SHI J, ZHENG L Y. Preparation and Properties of CNT/PLA Composites [J]. Acta Materiae Compositae Sinica, 2012, 29 (6):50⁃54.
29	PARK S H, LEE S G, KIM S H. Isothermal Crystallization Behavior and Mechanical Properties of Poly lactide/Carbon Nanotube Nanocomposites [J]. Composites: Part A, 2013, 46:11⁃18.
30	BEHERA K, CHANG Y H, YADAV M, et al. Enhanced Thermal Stability, Toughness, and Electrical Conductivity of Carbon Nanotube⁃Reinforced Biodegradable Poly (lactic acid)/Poly (ethylene oxide) Blend⁃Based Nanocomposites [J]. Polymer, 2020, 186:3 200⁃3 861.
31	WU D F, WU L, ZHANG M, et al. Viscoelasticity and Thermal Stability of Poly lactide Composites with Various Functionalized Carbon Nanotubes [J]. Polymer Degradation and Stability, 2008, 93 (8): 1 577⁃1 584.
32	蔡艳华. 聚乳酸/碳复合材料研究进展[J]. 现代塑料加工应用, 2014, 26 (4) : 58⁃60.
	CAI Y H. Research Process of Poly (lactic acid)/Carbon Composites [J]. Modern Plastics Processing and Applications. 2014, 26 (4):58⁃60.
33	KASHI S, GUPTA R K, BAUM T, et al. Phase Transition and Anomalous Rheological Behaviour of Poly lactide/Graphene Nanocomposites [J]. Composites Part B: Engineering, 2018, 135:25⁃34.
34	ISSAADI K, PILLIN I, HABI A, et al. Synergetic Association of Grafted PLA and Functionalized Graphene on the Properties of the Designed Nanocomposites [J]. Polymer Bulletin, 2016, 74 (4):997⁃1 010.
35	NASIR A, KAUSAR A, YOUNUS A. A Review on Preparation Properties and Applications of Polymeric Nanoparticle⁃Based Materials [J]. Polymer⁃Plastics Technology and Engineering, 2014, 54 (4):325⁃341.
36	MALKAPPA K, BANDYOPADHYAY J, RAY S S, Thermal Degradation Characteristic and Flame Retardancy of Poly lactide⁃Based Nanobiocomposites [J]. Molecules, 2018, 23 (10):2 648.
37	RAY S S, OKAMOTO M. New Poly lactide/Layered Silicate Nanocomposites [J]. Macromolecular Materials and Engineering, 2003, 288 (12):936⁃944.
38	WANG B, WAN T, ZENG W. Rheological and Thermal Properties of Poly lactide/Organic Montmorillonite Nanocomposites [J]. Journal of Applied Polymer Science, 2012, 125 (S2):364⁃371.
39	PAVLIDOU S, PAPASPYRIDES C D. A Review on Polymer–Layered Silicate Nanocomposites [J]. Progress in Polymer Science, 2008, 33 (12):1 119⁃1 198.
40	YU Z, LI B Q, CHU J Y, et al. Silica in Situ Enhanced PVA/Chitosan Biodegradable Films for Food Packages [J]. Carbohydr Polymer, 2018, 184:214⁃220.
41	ZHANG Y, DENG B Y, LIU Q S. Viscoelastic Behavior and Crystallization Property of Poly (lactic acid)/Silica Nanocomposite [J]. Journal of Reinforced Plastics and Composites, 2014, 33 (9):875⁃882.
42	MCDONOUGH K, N, ITRICH N, CASTEEL K, et al. Assessing the Biodegradability of Microparticles Disposed Down the Drain [J]. Chemosphere, 2017, 175:452⁃458.

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聚乳酸纳米复合材料流变性能研究进展

Research Progress in Rheological Behavior of Poly(lactic acid) Nanocomposites

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