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M-POE-g-MAH增韧PBT的力学性能和形貌

王向东,,,   

  1. 北京工商大学材料科学与工程系
  • 收稿日期:2008-09-25 修回日期:2008-09-25 出版日期:2017-10-10 发布日期:2017-10-10

STUDY ON MECHANICAL PROPERTIES AND IMPACT FRACTURE SURFACE MORPHOLOGY OF POLY(BUTYLENE TEREPHTHALATE) TOUGHED BY M-POE-g-MAH

  1. 44
  • Received:2008-09-25 Revised:2008-09-25 Online:2017-10-10 Published:2017-10-10

摘要: 研究了一种新型增韧剂(M-POE-g-MAH)对PBT树脂的增韧效果。与传统的纯POE-g-MAH增韧剂(POE-g-MAH)进行对比,考察了增韧剂的组成、用量对共混物力学性能的不同影响,并结合共混物的室温缺口冲击断面SEM照片,分析了共混物发生脆韧转变所对应的微观形貌特征。实验结果表明,在M-POE-g-MAH /PBT共混体系中,POE-g-MAH用量占体系10%左右时共混物发生明显的脆韧转变,而在传统的纯POE-g-MAH增韧剂/PBT共混体系中,POE-g-MAH用量为15%左右才使共混物发生脆韧转变。M-POE-g-MAH增韧PBT在性能和成本上具有较大的优势,所得共混物产品的性价比较高。

Abstract: Toughening effect on poly(butylenes Terephthalate) with a novel impact modifier(modified maleic anhydride grafted polyethylene-octene elastomer) (M-POE-g-MAH) was studied. Comparing to pure POE-g-MAH, Influence of impact modifier,s component and content on mechanical properties of blends was investigated. Using scanning electronic microscopy (SEM) photographs of impact fracture surface, morphologies responsible for brittle-tough transition were also analyzed. The results indicate that a brittle-tough transition occurred when POE-g-MAH content was up to 10% in M-POE-g-MAH/PBT blends, whereas brittle-tough transition occurred when POE-g-MAH content was up to 15% in POE-g-MAH/PBT blends. PBT toughened by M-POE-g-MAH impact modifier has more advantages in properties and cost, and its blend has a higher ratio of property to cost in contrast with pure POE-g-MAH impact modifier.

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