中国塑料 ›› 2018, Vol. 32 ›› Issue (06): 46-52.DOI: 10.19491/j.issn.1001-9278.2018.06.007

• 材料与性能 • 上一篇    下一篇

MCC对PLA/PPC复合材料力学性能与热稳定性的影响

桑东英1,程丹1,于光华1,刘雅欣1,张秀成2,刘丽华1,张野1   

  1. 1. 东北林业大学
    2. 东北林业大学理学院化学化工系,黑龙江省阻燃材料分子设计与制备重点实验室
  • 收稿日期:2017-12-12 修回日期:2017-12-27 出版日期:2018-06-26 发布日期:2018-07-31
  • 基金资助:
    黑龙江省应用技术研究与开发计划项目

Effect of MCC on Mechanical Performance and Thermal Stability of PLA/PPC Composites

  • Received:2017-12-12 Revised:2017-12-27 Online:2018-06-26 Published:2018-07-31
  • Supported by:
    Heilongjiang province technology research and development plan program of Heilongjiang province of China

摘要: 以微晶纤维素(MCC)作为改性剂,马来酸酐接枝聚乳酸(PLAgMAH)为界面相容剂,聚乳酸(PLA)、聚碳酸亚丙酯(PPC)为基体,通过熔融共混法制得PLA/PPC/MCC三元复合材料。采用控温拉伸、动态热分析、扫描电子显微镜以及热失重分析等方法研究了MCC对PLA/PPC的力学性能和热稳定性。结果表明,PLA/PPC/MCC三元复合材料的拉伸强度提高了12.7 %,玻璃化转变温度(Tg)提高了9.8 ℃;PLAgMAH的加入可以改善PLA/PPC/MCC三元复合材料的界面性质,从而提高力学性能和热稳定性;当PLAgMAH的添加量为5 %(质量分数,下同)时,三元复合材料在常温下的拉伸强度、弯曲强度和冲击强度分别提高了53.7 %、43.1 %和18.5 %;在60 ℃下三元复合材料的断裂强度提高了80 %;热降解温度以及最大失重温度与PLA/PPC相比分别提高了25.31 ℃和61.83 ℃。

Abstract: MCC/PLA/PPC composites were prepared by melt blending using PLA grafted with maleic anhydride (PLA-g-MAH) as a compatibilizer and MCC as a modifier. The effect of MCC on the mechanical properties, heat resistance and thermal stability of MCC/PLA/PPC composites were investigated by temperature-controlled stretching, dynamic thermal analysis, scanning electron microscopy and thermogravimetric analysis. The results shown that the tensile strength flexural strength was improved by 12.7 % and the glass translation temperature was increased by 9.8 ℃ when 40 wt% of MCC was added. On the other hand, the addition of 5 wt% PLA-g-MAH made the composites an increase in tensile strength by 53.7 %, in flexural strength by 43.1 % and in impact strength by 18 % due to an enhancement in interfacial adhesion. In this case, the breaking strength of the composites was also improved by 80 % at 60 ℃. Moreover, the thermal degradation temperature and maximum weight-loss temperature of the composites were improved by 25.31 and 61.83 ℃ compared to PLA/PPC composite, respectively.