中国塑料 ›› 2018, Vol. 32 ›› Issue (08): 40-45.DOI: 10.19491/j.issn.1001-9278.2018.08.007

• 材料与性能 • 上一篇    下一篇

聚丙烯共注射成型柱晶形成判据研究

孟健,陈金涛,李桂丽,陈兴元,李海梅   

  1. 郑州大学材料科学与工程学院
  • 收稿日期:2018-03-05 修回日期:2018-04-08 出版日期:2018-08-26 发布日期:2018-09-26
  • 基金资助:
    国家自然科学基金;国家重点实验室开放课题

Study on Evaluation Criterion of Formation of Polypropylene Cylindrical Crystal by Co-injection Molding

  • Received:2018-03-05 Revised:2018-04-08 Online:2018-08-26 Published:2018-09-26
  • Supported by:
    NSFC;Open Project of State Key Laboratory of Structural Analysis for Industrial Equipment

摘要: 以等规聚丙烯为原料,改变共注射成型中芯层熔体的注射速度,可获得不同工艺成型的试样,对试样进行结晶形貌观测,结合数值分析获得温度场、速度场、剪切力场,从能量变化角度,建立了共注射成型过程中柱晶形成的判据。结果表明,共注射成型制品存在模具—壳层、壳—芯层2个明显的剪切区,剪切处成型冷却过程中,易形成柱状晶体;对于板状共注塑试样,根据判据公式,其量化的柱晶形成条件为[170, 222]、[252, 458]。

Abstract: Co-injection molded isotactic polypropylene specimens were made at three different core injection rates of 20, 40,60 mm/s. The microstructure of the molded specimens was observed by polarizing optical microscopy. On the basis of the numerical and experimental results, the temperature field, shear rate field, and shear stress filed at the selected locations were calculated and a formation criteria equation for cylindrulite was established in terms of energy variation. Most of all, a quantitative criterion was established for the formation of polypropylene cylindrulite during the processing, which suggested that the cylindrulite could be formed in the range of [170, 222] and [252, 458].