中国塑料 ›› 2018, Vol. 32 ›› Issue (08): 58-64.DOI: 10.19491/j.issn.1001-9278.2018.08.010

• 材料与性能 • 上一篇    下一篇

多面体金属效果颜料的制备与应用

董建廷,叶倩,逯琪   

  1. 上海朗亿新材料科技有限公司
  • 收稿日期:2018-05-15 修回日期:2018-06-21 出版日期:2018-08-26 发布日期:2018-09-26

Preparation and Applications of Polyhedral Pigments with Metallic Effect

  • Received:2018-05-15 Revised:2018-06-21 Online:2018-08-26 Published:2018-09-26

摘要: 通过磁控溅射镀膜工艺,采用铝靶为溅射源,成功实现铝单质在微米级二氧化硅粉体表面的沉积,制备出新型多面体金属效果颜料。重点比较了多面体金属效果颜料与铝颜料在注塑制件中的流痕与熔接痕差异,同时,研究了多面体金属效果颜料对塑料基材物性的影响及加工工艺对多面体颜料所呈现表观效果的影响。最后,采用多面体金属效果颜料共混入塑料基材中成型出“无流痕”免喷涂制件。结果表明,与传统铝颜料相比,多面体金属效果颜料表现出良好的金属质感,流痕几乎完全消除,熔接痕亦大幅度减轻,并进一步从理论角度分析和解释了产生上述流痕和熔接痕差异的原因;与喷涂制件相比,“无流痕”免喷涂制件更环保,成本更低,表观效果更加独特,并得到了消费者认可,成功实现了商业化量产。

Abstract: In this work, with the help of magnetron sputtering coating process, the deposition of aluminum on the surface of micron-sized silica powders was carried out by using aluminum target as a sputtering source to achieve a new type polyhedral metallic pigment on a large scale. The differences between the polyhedron metallic pigments and traditional aluminum pigments were analyzed, which were mainly focused on the flow lines and weld lines in plastic parts. The results indicated that the polyhedron metallic pigments presented a better metallic texture in comparison with the traditional aluminum ones. Furthermore, the flow lines in the relevant parts almost disappeared completely, and the weld lines were also reduced significantly. The reasons for the differences between the flow and weld lines were further analyzed and explained theoretically. The effect of polyhedron metallic pigments on the physical properties of plastic parts was investigated, and meanwhile the effect of processing technology on the appearance of polyhedral pigments was also evaluated. The free-spraying parts with no flow lines could be directly injection molded by using a mixture of the polyhedral metallic pigments and thermoplastics. This processing procedure is more cost-effective and more ecologically friendly. The free-spraying parts have been approved by consumers due to a great commercial success.