中国塑料 ›› 2017, Vol. 31 ›› Issue (10): 1-5.DOI: 10.19491/j.issn.1001-9278.2017.10.001

• 综述 •    下一篇

磷系阻燃剂阻燃PET的研究进展

闫梦祥,张思源,王总帅,闰明涛   

  1. 河北大学化学与环境科学学院
  • 收稿日期:2017-03-27 修回日期:2017-05-29 出版日期:2017-10-26 发布日期:2017-10-25

Research Progress in Phosphorus Flame Retardants for Polyesters

  • Received:2017-03-27 Revised:2017-05-29 Online:2017-10-26 Published:2017-10-25

摘要: 综述了磷系阻燃剂阻燃聚对苯二甲酸乙二醇酯(PET)的改性方法,其中主要有共聚阻燃改性、共混阻燃改性、后处理法以及一些新技术。重点介绍了共聚阻燃改性中以2羧乙基苯基次膦酸(CEPPA)为代表的磷系阻燃剂以及共混阻燃改性中所用的各种阻燃剂,并指出了PET阻燃的研究方向。目前,PET的阻燃主要向着低毒、低烟、无卤化方向发展,而且开发新型或复配无卤阻燃剂已经成为PET阻燃的必然趋势。

Abstract: This paper overviewed flameretardant modification methods for polyesters, which focused on the copolymerization, blending and postprocessing methods for flameretardant modification, and also introduced some new modification technologies. Furthermore, 2carboxyethyl(phenylphosphinic) acid (CEPPA) as a representative phosphoruscontaining flame retardant used for polyesters was introduced in detail, and future development direction of flameretardant polyesters was proposed. It should be pointed out that low toxicity, low smoke and halogenfree flame retardants for polyesters are the current direction in development, but the development of new types of halogenfree flame retardants will be a future trend.