中国塑料 ›› 2018, Vol. 32 ›› Issue (07): 47-51.DOI: 10.19491/j.issn.1001-9278.2018.07.007

• 材料与性能 • 上一篇    下一篇

碱处理竹纤维对EVA结构和性能的影响

周松1,闫珂华2,鲁超飞1,罗玉梅1,白小东1   

  1. 1. 西南石油大学
    2. 西南石油大学材料科学与工程学院
  • 收稿日期:2018-01-30 修回日期:2018-03-20 出版日期:2018-07-26 发布日期:2018-08-24

Effect of Bamboo Fiber Due to Alkali Treatment on the Structure and Properties of EVA

  • Received:2018-01-30 Revised:2018-03-20 Online:2018-07-26 Published:2018-08-24

摘要: 采用NaOH碱液处理竹纤维(BF),通过双螺杆挤出和注射成型制备了乙烯醋酸乙烯酯共聚物(EVA)/BF复合材料。用红外光谱﹑扫描电子显微镜﹑差示扫描量热仪﹑X射线衍射仪和热失重分析等表征了材料的形貌、组成结构和热性能,测试了力学性能和熔体流动速率。结果表明,BF对EVA结晶有异相成核作用;BF使EVA的压缩强度和模量明显增大,EVA/30 %~40 % BF的拉伸强度接近或超过纯EVA;EVA/BF在熔体加工中保持较高的热稳定性能,源于碱处理去除了BF中的胶质物、EVA与BF较好的界面结合以及EVA较低的熔体加工温度。

Abstract: Bamboo fibers were treated with NaOH solution and the ethylene-vinyl acetate copolymer/ bamboo fiber (EVA/BF) composites were prepared by a twin screw extruder and injection molding, and analyzed by IR, SEM, DSC, XRD, TG, MFI and mechanical testing. The results demonstrated that BF had heterogeneous nucleation effect on crystallization of EVA. The compressive modulus and strength of EVA increased significantly with the addition of BF, and the tensile strength of EVA/30-40% BF were close to or higher than that of pure EVA. Relatively higher thermal stability of EVA/BF composites during the melt processing results from the removal of the cementing materials of BF during alkali treatment, better interfacial adhesion betweed EVA and BF, and lower melt processing temperature of EVA.