中国塑料 ›› 2018, Vol. 32 ›› Issue (09): 42-48.DOI: 10.19491/j.issn.1001-9278.2018.09.007

• 材料与性能 • 上一篇    下一篇

PE-LD/桉木粉复合材料的制备及其性能研究

丰波,谢俊康,李富强,韩巧宁,廖霞,徐伟华,刘祖广   

  1. 广西民族大学化学化工学院
  • 收稿日期:2018-03-15 修回日期:2018-04-23 出版日期:2018-09-26 发布日期:2018-10-25
  • 基金资助:
    广西大学生创新创业训练计划项目

Preparation and Properties of Wood Plastic Composites Based on PE-LD and Eucalyptus Flour Powders

  • Received:2018-03-15 Revised:2018-04-23 Online:2018-09-26 Published:2018-10-25
  • Supported by:
    Guangxi college students' innovative entrepreneurial training program

摘要: 以自制的低密度聚乙烯接枝马来酸酐(PE-LD-g-MAH)为改性剂,分别使用双螺杆挤出机和开放式炼胶机制备了PE-LD/桉木粉复合材料。采用模压成型法制备了试片,探究了模压温度、模压时间、改性剂用量和不同的制备方法对木塑复合材料拉伸强度和缺口冲击强度的影响,并采用扫描电子显微镜、傅里叶变换红外光谱对其形貌和结构进行了表征。结果表明,木塑复合材料较适宜的模压温度为160 ℃,模压时间为10 min;添加PE-LD-g-MAH并采用开放式炼胶机制备的复合材料的拉伸强度由空白样的16.53 MPa提高到24.46 MPa ,缺口冲击强度由2.04 kJ/m2提高到458 kJ/m2;PE-LD-g-MAH与木粉表面羟基发生了酯化反应,增加了界面黏结强度,从而提高了木塑复合材料的力学性能。

Abstract: The PE-LD/eucalyptus flour powders wood plastic composites were prepared by a twin-screw extruder and an open-type refine machine using PE-LD-g-MAH a compatibilizer, and the effects of molding temperature, molding time, PE-LD-g-MAH concentration and preparation methods on the tensile strength and notched impact strength of the composites were investigated. The morphology and chemical structure of the composites were characterized by SEM and FTIR. The results indicated that the optimum molding temperature and time is 160 ℃ and 10 min for the preparation of composites, and the use of the open-type refine machine and PE-LD-g-MAH led to the excellent mechanical properties for the composites due to a better dispersion and interface bonding strength of eucalyptus flour powders. The tensile strength of composites increased from 16.53 MPa to 24.46 MPa, and their notched impact strength increased from 2.04 kJ/m2 to 4.58 kJ/m2. The improvement in mechanical properties was due to the enhanced interface-bonding strength derived from the esterification reaction between PE-LD-g-MAH and the hydroxyl groups on the surface of eucalyptus flour powders.