中国塑料 ›› 2019, Vol. 33 ›› Issue (2): 8-12,34.DOI: 10.19491/j.issn.1001-9278.2019.02.002

• 材料与性能 • 上一篇    下一篇

EVA阻燃材料的制备与性能研究

颜渊巍,高玮,熊昌义,胡钊,黄自华   

  1. 株洲时代新材料科技股份有限公司
  • 收稿日期:2018-09-17 修回日期:2018-09-28 出版日期:2019-02-26 发布日期:2019-03-26
  • 基金资助:
    湖南省自然科学基金青年基金(2017JJ3531)

Study on Preparation and Properties of Flame-Retardant EVA Material

  • Received:2018-09-17 Revised:2018-09-28 Online:2019-02-26 Published:2019-03-26

摘要: 通过极限氧指数、垂直燃烧、烟密度、锥形量热、扫描电子显微镜等表征方法,研究了不同用量自制哌嗪类膨胀阻燃剂(IFR)对乙烯醋酸乙烯共聚物(EVA)的阻燃作用。结果表明,添加30 %(质量分数,下同)IFR的EVA材料极限氧指数能达到37 %,UL 94垂直燃烧达到V-0级,有焰、无焰烟密度均很低,热释放速率峰值降至156 kW/m2,仅仅只有纯EVA的21.8 %,燃烧后形成了致密的膨胀炭层;该阻燃材料具有很低的吸湿率,力学性能保持较好,且能满足RoHS环保要求。

Abstract: The flame-retardant effect of the self-made piperazine intumescent flame retardant (IFR) on ethylene-vinyl acetate copolymer (EVA) was investigated by limited oxygen index (LOI) measurement, vertical burning experiment, smoke density, cone calorimetry and scanning electron microscopy. The results indicated that the flame-retardant EVA material achieved the LOI of 37 vol% with the addition of 30 wt% IFR and reached a V-0 classification in the UL 94 vertical burning experiment. The smoke density of flame-retarded EVA material was very low under the combustion conditions with flame and without flame, and their peak heat release rate decreased to 156 kW/m2, which was only equal to 21.8 % of the value for pure EVA. A dense expanded carbon layer was formed after combustion. The flame-retarded EVA material exhibits a low moisture absorption rate and good mechanical properties and therefore can meet the requirements of the RoHS environmental protection.