中国塑料 ›› 2019, Vol. 33 ›› Issue (8): 89-94.DOI: 10.19491/j.issn.1001-9278.2019.08.015

• 塑料与环境 • 上一篇    下一篇

回收料对聚乙烯管材专用料及制品性能的影响研究

卢晓英1,王宇杰1,徐春燕1,蔡玉东1,朱光宇2,孔霏1,杨晓彦1,吕畅1,王艳芳1,黄强1,于建红3   

  1. 1. 中国石油天然气股份有限公司石油化工研究院
    2. 中国石油石油化工研究院
    3. 吉林石化分公司
  • 收稿日期:2019-03-08 修回日期:2019-05-06 出版日期:2019-08-26 发布日期:2019-08-26

Study on Effect of Recycled Materials on Properties of Polyethylene Raw Material Specially Used for Pipes and Its Products

  • Received:2019-03-08 Revised:2019-05-06 Online:2019-08-26 Published:2019-08-26

摘要: 研究了聚乙烯管材新料和回收料或再生料中物性差异及回收料对管材制品性能的影响;开展了管材新料与典型回收料不同比例掺混试验,系统研究了掺混料的力学性能、抗氧化性能和流变性能。结果表明,聚乙烯管材或原料中灰分、熔体流动速率、氧化诱导时间和金属元素含量的测定可以有效将再生料及其制品与管材新料及其制品区分开来;铁和钙元素含量的测定可以有效鉴定出管材原料及其制品中是否掺混有管材再生料或回收料;本项目研究成果有望应用于聚烯烃塑料管道标准的制修订,对规范塑料管道行业健康发展发挥重要作用。

Abstract: In this paper we investigated the differences of physical properties between the virgin and recycled polyethylene raw material specially used for pipe, and the effect of recycled PE on the properties of pipes was also studied. The results indicated that melt flow index, ash content, oxidation induction time and metal element content could be considered as effective indicators for identifying the virgin/recycled PE materials for pipes. Moreover, a mixing experiment was performed to prepare the compounds with different contents of typical recycled PE materials. The mechanical properties, antioxidant performance, metal contents and rheological behaviors of the compounds were evaluated intensively. The investigation showed that the presence of recycled PE material in the pipes or raw materials could be effectively distinguished by detecting the content of iron and calcium. The research results obtained from this work can be used for the revision of the standard specification for polyolefin plastic pipeline and will also make a contribution to the development of plastic pipeline industry.