中国塑料 ›› 2013, Vol. 27 ›› Issue (11): 34-38.DOI: 10.19491/j.issn.1001-9278.2013.11.006

• 材料与性能 • 上一篇    下一篇

玄武岩纤维增强PVDF/PP/PETG共混物及性能的研究

宋剑斌,马长城,陈丽红,刘建勋,杨文斌   

  1. 福建农林大学
  • 收稿日期:2013-08-05 修回日期:2013-09-04 出版日期:2013-11-26 发布日期:2013-11-26
  • 基金资助:
    国家自然科学基金No.31170535和30771683;福建教育厅基金JK2013012

Preparation and Performance of Basalt Fiber Reinforced PVDF/PP/PETG Blends

  • Received:2013-08-05 Revised:2013-09-04 Online:2013-11-26 Published:2013-11-26

摘要: 通过熔融共混法制备了聚偏氟乙烯/聚丙烯/聚对苯二甲酸乙二醇1,4环己二醇酯(PVDF/PP/PETG)共混物,利用玄武岩纤维对其进行增强改性,并采用扫描电子显微镜、转矩流变仪、维卡软化点测试仪等测试仪器对共混物的形态、黏度、耐热性和力学性能等进行了研究。结果表明,230 ℃时,共混物中PVDF、PP和PETG属两两不相容体系,PVDF和PP呈现连续相结构,而PETG则以球状形态分散在体系中;经玄武岩纤维增强改性后,复合材料的拉伸强度和弯曲强度随着玄武岩纤维含量的增加而增大,且当其含量为30 %(质量分数,下同)时,复合材料的拉伸强度和弯曲强度分别增加到44.0 MPa和67.9 MPa;共混物的维卡软化点从126.7 ℃提高到141.7 ℃。

Abstract: PVDF/PP/PETG/basalt fiber composites were prepared by a melting blending method. The rheological behavior, morphology, mechanical properties, and heat resistance of the blends were investigated using rotary rheometer,scanning electron microscopy, material testing machine, and Vicat softening point machine in detail. It was found that PP, PVDF and PETG were pairwise immiscible, in which PP and PVDF formed a bicontinuoud phase and PETG presented in the system as spherulite particles. The poor mechanical properties of PVDF/PP/PETG blends were improved after basalt fiber was introduced. The tensile strength and flexural strength of PVDF/PP/PETG composite increased to 21.9 MPa and 44 MPa when the content of basalt fiber was 30 wt%. Vicat softening point of PVDF/PP/PETG composite was increased from 126.7 ℃ to 141.7 ℃.

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