中国塑料 ›› 2014, Vol. 28 ›› Issue (07): 22-26 .DOI: 10.19491/j.issn.1001-9278.2014.07.005

• 材料与性能 • 上一篇    下一篇

固化促进剂种类对集成电路封装材料固化行为的影响

李光1,杨明山2,张卓冯徐根金洪广   

  1. 1. 北京石油化工学院;北京化工大学2. 北京石油化工学院
  • 收稿日期:2013-11-22 修回日期:2014-01-10 出版日期:2014-07-26 发布日期:2014-07-26

Effect of Curing Accelerator Type on Curing Behavior of IC Packaging Materials

  • Received:2013-11-22 Revised:2014-01-10 Online:2014-07-26 Published:2014-07-26

摘要: 选用酚醛树脂为固化剂,分别以2-甲基咪唑和三苯基磷为固化促进剂,制备了集成电路封装用环氧树脂模塑料。用非等温差示扫描量热(DSC)法研究了固化促进剂种类对环氧模塑料的固化行为的影响,利用Kissinger方程、Crane方程和Ozawa方程计算出了环氧树脂模塑料的固化活化能、反应级数等固化反应动力学参数,推导出了固化过程的凝胶化温度、固化温度、后处理温度等最佳固化工艺条件。

关键词: 酚醛树脂, 集成电路, 环氧模塑料, 固化动力学

Abstract: Epoxy molding compounds for integrated circuits (IC) packaging were prepared by using phenolic resin as a curing agent, either 2-methyl imidazole or triphenyl phosphine as a curing accelerator. The curing behavior of the compounds was investigated by non-isothermal DSC method. Based on Kissinger, Crane, and Ozawa methods, the kinetic parameters such as activation energy and reaction order of the curing reaction were obtained. The characteristic temperatures of the curing process such as gel temperature, curing temperature, and postcuring temperature were calculated by extrapolation. It was found that the compound using 2-methyl imidazole had a lower activation energy compared with that using triphenyl phosphine.

Key words: phenolic resin, intergrated circuit, epoxy molding compound, curing kinetics