中国塑料 ›› 2025, Vol. 39 ›› Issue (1): 1-5.

• 材料与性能 •    下一篇

高性能膜料ACP7000F的工业生产及性能研究

林晚心,高念,李颖   

  1. 中石化(北京)化工研究院有限公司
  • 收稿日期:2024-07-31 修回日期:2024-08-27 出版日期:2025-01-26 发布日期:2025-01-26

Industrial production and performance of high⁃performance film⁃grade PE⁃HD resin( ACP7000F)

  • Received:2024-07-31 Revised:2024-08-27 Online:2025-01-26 Published:2025-01-26

摘要: 采用BCE-H200催化剂在350 kt·a-1 Hostalen ACP工艺高密度聚乙烯(HDPE)装置完成ACP7000F膜料的工业试验。利用熔体流动速率、凝胶渗透色谱、力学性能测试等方法考察催化剂、聚乙烯粉料及膜料的综合性能。试验结果表明,BCE-H200催化剂具有较高的活性,较平稳的氢调敏感性和优异的共聚性能。与参比催化剂相比,BCE-H200催化剂活性提高87.5%,氢气单耗降低12.5%,1-丁烯单耗降低13.1%,所得聚乙烯粉料细粉少、平均粒径更大。由BCE-H200催化剂生产的膜料各项力学性能更优,高负荷下鱼眼数量更少,符合企业生产标准。BCE-H200催化剂可替代进口催化剂生产高性能膜料树脂。经分析,参比催化剂膜料上形成的鱼眼主要组成为高分子量、低结晶度的聚乙烯。

Abstract: Commercial trial on HDPE unit of 350 kt·a-1 Hostalen ACP process for producing ACP7000F film grade resin by BCE-H200 catalyst had been succeeded. Using melt flow rate (MFR), gel permeability chromatography (GPC) and mechanical tests to characterise general performance of catalyst, polyethylene (PE) powder and film resin. Tests result showed that BCE-H200 catalyst had higher activity, stabler hydrogen response and excellent copolymerisation ability. Compared to reference catalyst, the activity of BCE-H200 catalyst improved 87.5%, hydrogen consumption decreased 12.5%, butene-1 consumption decreased 13.1%, fines were less, and average particle size of its PE powder was bigger. Mechanical properties of film resin produced by BCE-H200 catalyst was better, less gel under high load, which met production standard of customer. Imported catalyst can be replaced by BCE-H200 catalyst for producing high performance film grade resin. Researching on gel from reference film showed that its content was PE of high molecular weight and low crystallinity.