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© 《China Plastics》
China Plastics ›› 2022, Vol. 36 ›› Issue (2): 139-146.DOI: 10.19491/j.issn.1001-9278.2022.02.020
• Standard and Test • Previous Articles Next Articles
REN Ping, ZHAO Jie, JU Ying, WANG Yu, SHEN Kangjun, LIU Shu()
Received:
2021-08-19
Online:
2022-02-26
Published:
2022-02-23
CLC Number:
REN Ping, ZHAO Jie, JU Ying, WANG Yu, SHEN Kangjun, LIU Shu. Migration risk and regulatory control of primary aromatic amines in food contact materials[J]. China Plastics, 2022, 36(2): 139-146.
序号 | 化学名称 | CAS号 | 文献 | 法规及标准 | |
---|---|---|---|---|---|
欧盟 | 中国 | ||||
1 | 4,4’⁃次甲基⁃双⁃(2⁃氯苯胺) | 101⁃14⁃4 | [ | 法规[ | 标准[ |
2 | 4,4’⁃二氨基二苯甲烷(4,4'⁃亚甲基二苯胺) | 101⁃77⁃9 | [ | ||
3 | 4,4’⁃二氨基二苯醚 | 101⁃80⁃4 | [ | ||
4 | 对氯苯胺 | 106⁃47⁃8 | [ | ||
5 | 3,3’⁃二甲氧基联苯胺 | 119⁃90⁃4 | [ | ||
6 | 3,3’⁃二甲基联苯胺(邻联甲苯胺) | 119⁃93⁃7 | [ | ||
7 | 3⁃氨基对甲苯甲醚(2⁃甲氧基⁃5⁃甲基苯胺) | 120⁃71⁃8 | [ | ||
8 | 2,4,5⁃三甲基苯胺 | 137⁃17⁃7 | [ | ||
9 | 4,4’⁃二氨基二苯硫醚 | 139⁃65⁃1 | [ | ||
10 | 对氨基偶氮苯 | 60⁃09⁃3 | [ | ||
11 | 2,4⁃二氨基苯甲醚 | 615⁃05⁃4 | [ | ||
12 | 3,3’⁃二甲基⁃4,4’⁃二氨基二苯甲烷 | 838⁃88⁃0 | [ | ||
13 | 邻甲氧基苯胺(邻氨基苯甲醚、2⁃甲氧基苯胺) | 90⁃04⁃0 | [ | ||
14 | 2⁃萘胺 | 91⁃59⁃8 | [ | ||
15 | 3,3’⁃二氯联苯胺 | 91⁃94⁃1 | [ | ||
16 | 4⁃氨基联苯 | 92⁃67⁃1 | [ | ||
17 | 联苯胺 | 92⁃87⁃5 | [ | ||
18 | 邻甲苯胺 | 95⁃53⁃4 | [ | ||
19 | 4⁃氯邻甲苯胺 | 95⁃69⁃2 | [ | ||
20 | 2,4⁃二氨基甲苯 | 95⁃80⁃7 | [ [ | ||
21 | 邻氨基偶氮甲苯 | 97⁃56⁃3 | [ | ||
22 | 2⁃氨基⁃4⁃硝基甲苯 | 99⁃55⁃8 | [ | ||
23 | 间苯二胺 | 108⁃45⁃2 | [ | 法规[ | |
24 | 4,4⁃亚甲基双(3⁃氯⁃2,6⁃二乙基苯胺) | 106246⁃33⁃7 | — | 法规[ | - |
25 | 2,6⁃二氨基甲苯 | 823⁃40⁃5 | [ | 指南[ | - |
26 | 对苯二胺 | 106⁃50⁃3 | [ | 标准[ | |
27 | 2,6⁃二甲基苯胺 | 87⁃62⁃7 | [ | ||
28 | 苯胺 | 62⁃53⁃3 | [ | ||
29 | 2,4⁃二甲基苯胺 | 95⁃68⁃1 | [ | ||
30 | 2,4’⁃二氨基二苯甲烷 | 1208⁃52⁃2 | — | - | |
31 | 2,2’⁃二氨基二苯甲烷 | 6582⁃52⁃1 | — | - | |
32 | 4,4’⁃磺酰基双苯胺 | 80⁃08⁃0 | — | - | 标准[ |
33 | 对甲氧基苯胺 | 104⁃94⁃9 | [ | - | - |
34 | 对甲苯胺 | 106⁃49⁃0 | [ | - | - |
35 | 间氯苯胺 | 108⁃42⁃9 | [ | - | - |
36 | 1,5⁃二氨基萘(1,5⁃萘二胺) | 2243⁃62⁃1 | [ | - | - |
37 | 3,5⁃二氯苯胺 | 626⁃43⁃7 | [ | - | - |
38 | 2⁃氨基联苯 | 90⁃41⁃5 | [ | - | - |
39 | 3.4⁃二氯苯胺 | 95⁃76⁃1 | [ | - | - |
40 | 3⁃甲基苯胺 | 108⁃44⁃1 | [ | - | - |
41 | 均三甲基苯胺 | 88⁃05⁃1 | [ | - | - |
序号 | 化学名称 | CAS号 | 文献 | 法规及标准 | |
---|---|---|---|---|---|
欧盟 | 中国 | ||||
1 | 4,4’⁃次甲基⁃双⁃(2⁃氯苯胺) | 101⁃14⁃4 | [ | 法规[ | 标准[ |
2 | 4,4’⁃二氨基二苯甲烷(4,4'⁃亚甲基二苯胺) | 101⁃77⁃9 | [ | ||
3 | 4,4’⁃二氨基二苯醚 | 101⁃80⁃4 | [ | ||
4 | 对氯苯胺 | 106⁃47⁃8 | [ | ||
5 | 3,3’⁃二甲氧基联苯胺 | 119⁃90⁃4 | [ | ||
6 | 3,3’⁃二甲基联苯胺(邻联甲苯胺) | 119⁃93⁃7 | [ | ||
7 | 3⁃氨基对甲苯甲醚(2⁃甲氧基⁃5⁃甲基苯胺) | 120⁃71⁃8 | [ | ||
8 | 2,4,5⁃三甲基苯胺 | 137⁃17⁃7 | [ | ||
9 | 4,4’⁃二氨基二苯硫醚 | 139⁃65⁃1 | [ | ||
10 | 对氨基偶氮苯 | 60⁃09⁃3 | [ | ||
11 | 2,4⁃二氨基苯甲醚 | 615⁃05⁃4 | [ | ||
12 | 3,3’⁃二甲基⁃4,4’⁃二氨基二苯甲烷 | 838⁃88⁃0 | [ | ||
13 | 邻甲氧基苯胺(邻氨基苯甲醚、2⁃甲氧基苯胺) | 90⁃04⁃0 | [ | ||
14 | 2⁃萘胺 | 91⁃59⁃8 | [ | ||
15 | 3,3’⁃二氯联苯胺 | 91⁃94⁃1 | [ | ||
16 | 4⁃氨基联苯 | 92⁃67⁃1 | [ | ||
17 | 联苯胺 | 92⁃87⁃5 | [ | ||
18 | 邻甲苯胺 | 95⁃53⁃4 | [ | ||
19 | 4⁃氯邻甲苯胺 | 95⁃69⁃2 | [ | ||
20 | 2,4⁃二氨基甲苯 | 95⁃80⁃7 | [ [ | ||
21 | 邻氨基偶氮甲苯 | 97⁃56⁃3 | [ | ||
22 | 2⁃氨基⁃4⁃硝基甲苯 | 99⁃55⁃8 | [ | ||
23 | 间苯二胺 | 108⁃45⁃2 | [ | 法规[ | |
24 | 4,4⁃亚甲基双(3⁃氯⁃2,6⁃二乙基苯胺) | 106246⁃33⁃7 | — | 法规[ | - |
25 | 2,6⁃二氨基甲苯 | 823⁃40⁃5 | [ | 指南[ | - |
26 | 对苯二胺 | 106⁃50⁃3 | [ | 标准[ | |
27 | 2,6⁃二甲基苯胺 | 87⁃62⁃7 | [ | ||
28 | 苯胺 | 62⁃53⁃3 | [ | ||
29 | 2,4⁃二甲基苯胺 | 95⁃68⁃1 | [ | ||
30 | 2,4’⁃二氨基二苯甲烷 | 1208⁃52⁃2 | — | - | |
31 | 2,2’⁃二氨基二苯甲烷 | 6582⁃52⁃1 | — | - | |
32 | 4,4’⁃磺酰基双苯胺 | 80⁃08⁃0 | — | - | 标准[ |
33 | 对甲氧基苯胺 | 104⁃94⁃9 | [ | - | - |
34 | 对甲苯胺 | 106⁃49⁃0 | [ | - | - |
35 | 间氯苯胺 | 108⁃42⁃9 | [ | - | - |
36 | 1,5⁃二氨基萘(1,5⁃萘二胺) | 2243⁃62⁃1 | [ | - | - |
37 | 3,5⁃二氯苯胺 | 626⁃43⁃7 | [ | - | - |
38 | 2⁃氨基联苯 | 90⁃41⁃5 | [ | - | - |
39 | 3.4⁃二氯苯胺 | 95⁃76⁃1 | [ | - | - |
40 | 3⁃甲基苯胺 | 108⁃44⁃1 | [ | - | - |
41 | 均三甲基苯胺 | 88⁃05⁃1 | [ | - | - |
材质 | 检测样品 | 芳香胺种类 | 迁移量/mg·kg-1 | 检出性 |
---|---|---|---|---|
聚酰胺6、 聚酰胺66 | 聚酰胺餐具(勺、钳等) | — | 0.01~6.86 | 阳性 |
黑色餐具[ | 4,4’⁃二氨基二苯甲烷 | 20 | 阳性 | |
苯胺 | 0.1 | 阳性 | ||
对苯二胺、间苯二胺、2,4⁃二氨基甲苯、2,6⁃二氨基甲苯、邻氨基苯甲醚、联苯胺、邻甲苯胺、2,4⁃二甲基苯胺、2,6⁃二甲基苯胺、3,3⁃二甲基联苯胺、4⁃氨基联苯、4⁃氯⁃2⁃甲基苯胺、4⁃氯苯胺、5⁃甲氧基⁃2⁃甲基苯胺 | — | 阳性 | ||
绿色面包夹[ | 邻氯苯胺 | 0.002 | 阳性 | |
聚酰胺餐具[ | 4,4’⁃二氨基二苯甲烷 | 0.02 | 阳性 |
材质 | 检测样品 | 芳香胺种类 | 迁移量/mg·kg-1 | 检出性 |
---|---|---|---|---|
聚酰胺6、 聚酰胺66 | 聚酰胺餐具(勺、钳等) | — | 0.01~6.86 | 阳性 |
黑色餐具[ | 4,4’⁃二氨基二苯甲烷 | 20 | 阳性 | |
苯胺 | 0.1 | 阳性 | ||
对苯二胺、间苯二胺、2,4⁃二氨基甲苯、2,6⁃二氨基甲苯、邻氨基苯甲醚、联苯胺、邻甲苯胺、2,4⁃二甲基苯胺、2,6⁃二甲基苯胺、3,3⁃二甲基联苯胺、4⁃氨基联苯、4⁃氯⁃2⁃甲基苯胺、4⁃氯苯胺、5⁃甲氧基⁃2⁃甲基苯胺 | — | 阳性 | ||
绿色面包夹[ | 邻氯苯胺 | 0.002 | 阳性 | |
聚酰胺餐具[ | 4,4’⁃二氨基二苯甲烷 | 0.02 | 阳性 |
材质 | 检测样品 | 芳香胺种类 | 检测结果/mg·kg-1 | 检出性 |
---|---|---|---|---|
聚丙烯 | 粉色餐具[ | 苯胺 | 0.025(迁移量) | 阳性 |
橙黄色冰格[ | 2,4(6)⁃二甲基苯胺 | 0.004 6(迁移量) | 阳性 | |
苯乙烯⁃丙烯腈共聚物 | 黄色水杯[ | 2⁃氨基联苯 | 0.051(残留量) 0.008(迁移量) | 阳性 |
丙烯腈⁃丁二烯⁃苯乙烯共聚物 | 褐色榨汁机[ | 苯胺 | 0.047(残留量) | 阳性 |
材质 | 检测样品 | 芳香胺种类 | 检测结果/mg·kg-1 | 检出性 |
---|---|---|---|---|
聚丙烯 | 粉色餐具[ | 苯胺 | 0.025(迁移量) | 阳性 |
橙黄色冰格[ | 2,4(6)⁃二甲基苯胺 | 0.004 6(迁移量) | 阳性 | |
苯乙烯⁃丙烯腈共聚物 | 黄色水杯[ | 2⁃氨基联苯 | 0.051(残留量) 0.008(迁移量) | 阳性 |
丙烯腈⁃丁二烯⁃苯乙烯共聚物 | 褐色榨汁机[ | 苯胺 | 0.047(残留量) | 阳性 |
建议书名称 | 要求 |
---|---|
BfRIX[ | 食品接触制品中PAAs释放量为不得检出,PAAs总量检出限为0.01 mg/kg(食品或食品模拟物)。此外,在《欧盟物质和混合物的分类、标签和包装法规》 |
BfRXXI[ | PAAs的迁移量不超过50 μg/L。 |
BfRXXVIII[ | 溶剂挥发后,食品接触用聚氨酯黏合剂1m2成型品中残留的聚氨酯黏合剂不得超过10 g,食品或食品模拟物中不得检出迁移的溶剂或胺类物质。 |
BfRXXXVI[ | PAAs在食品接触制品中释放量为不得检出,PAAs总量检出限为0.01 mg/kg(食品或食品模拟物)。此外,在CLP法规(EC)1272/2008中分类为1A和1B类致癌物的PAAs的释放量为不得检出,单个PAAs的检出限为0.002 mg/kg(食品或食品模拟物)。 |
BfRXLl[ | 成品中不可检出异氰酸酯基团和PAAs。 |
BfRLI[ | PAAs在食品接触制品中释放量为不得检出,PAAs总量检出限为0.01 mg/kg(食品或食品模拟物)。此外,在CLP法规(EC)1272/2008中分类为1A和1B类致癌物的PAAs的释放量为不得检出,单个PAAs的检出限为0.002 mg/kg(食品或食品模拟物)。列入(EU)No10/2011附件Ⅰ中 |
建议书名称 | 要求 |
---|---|
BfRIX[ | 食品接触制品中PAAs释放量为不得检出,PAAs总量检出限为0.01 mg/kg(食品或食品模拟物)。此外,在《欧盟物质和混合物的分类、标签和包装法规》 |
BfRXXI[ | PAAs的迁移量不超过50 μg/L。 |
BfRXXVIII[ | 溶剂挥发后,食品接触用聚氨酯黏合剂1m2成型品中残留的聚氨酯黏合剂不得超过10 g,食品或食品模拟物中不得检出迁移的溶剂或胺类物质。 |
BfRXXXVI[ | PAAs在食品接触制品中释放量为不得检出,PAAs总量检出限为0.01 mg/kg(食品或食品模拟物)。此外,在CLP法规(EC)1272/2008中分类为1A和1B类致癌物的PAAs的释放量为不得检出,单个PAAs的检出限为0.002 mg/kg(食品或食品模拟物)。 |
BfRXLl[ | 成品中不可检出异氰酸酯基团和PAAs。 |
BfRLI[ | PAAs在食品接触制品中释放量为不得检出,PAAs总量检出限为0.01 mg/kg(食品或食品模拟物)。此外,在CLP法规(EC)1272/2008中分类为1A和1B类致癌物的PAAs的释放量为不得检出,单个PAAs的检出限为0.002 mg/kg(食品或食品模拟物)。列入(EU)No10/2011附件Ⅰ中 |
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