中国塑料 ›› 2009, Vol. 23 ›› Issue (04): 53-57 .DOI: 10.19491/j.issn.1001-9278.2009.04.013

• 加工与应用 • 上一篇    下一篇

单体浇铸聚酰胺6/Kevlar纤维复合材料制备的温度场分析

张星 程雷 李宝铭 王灿耀 郑玉婴   

  1. 福州大学化学化工学院化工系 福建省福州大学化学化工学院化工系
  • 收稿日期:2008-12-09 修回日期:2008-12-18 出版日期:2009-04-26 发布日期:2009-04-26

Temperature field of Kevlar Fiber/MC nylon 6 composites during preparation process

  

  • Received:2008-12-09 Revised:2008-12-18 Online:2009-04-26 Published:2009-04-26

摘要: 采用有限差分法,将聚合热和结晶潜热当作内部热源,对Kevlar纤维(KF)/MC尼龙6复合材料成型的聚合和结晶过程进行数值模拟。模拟结果表明:模具温度为145-160℃时,结晶在很大程度上影响着MC尼龙6浇铸体系的温度变化,随着模具温度的升高,影响变小,当模具温度为175℃时,结晶对体系温度的影响可以忽略。随着纤维含量的增多,反应结束的最高温度降低。将模拟结果和试验结果进行比较,反应一开始,试验值远远滞后于模拟值,然后逐渐地趋于一致,二者偏离的原因主要是己内酰胺活性料吸热慢、采用密度法测结晶度和实际纤维的分散不均。

关键词: Kevlar纤维, MC尼龙6, 温度场, 有限差分法

Abstract: Numerical Simulation of cast-forming process and crystallization of Kevlar fiber reinforced MC nylon6 was performed with polymerization and latent heat as internal heat sources by finite difference method. Crystallization had great effect on the temperature of reaction system when the mould temperature ranged from 145 to 160℃. However, the effect weakened with the drop of mould temperature and disappeared as the mould temperature reached 175℃. The highest temperature of reaction system reduced with increase of the fiber mass. Compared with the simulated results, experimental results falled far behind at the reaction beginning, and they agreed well with each other later. What the reasons for the deviation between simulated results and experimental results are slow endothermic velocity, crystallinity tested by density method and fibers distributed non–uniformly.

Key words: Kevlar fiber, MC nylon 6, temperature field, finite difference method

中图分类号: