中国塑料 ›› 2014, Vol. 28 ›› Issue (08): 52-57.DOI: 10.19491/j.issn.1001-9278.2014.08.011

• 加工与应用 • 上一篇    

强剪切作用对全淀粉塑料结构和性能的影响

张佳,,,苏阳   

  1. 天津工业大学
  • 收稿日期:2014-03-07 修回日期:2014-06-18 出版日期:2014-08-26 发布日期:2014-08-26

Effect of Strong Shearing Action on the Structure and Properties of Fullstarch Plastics

  • Received:2014-03-07 Revised:2014-06-18 Online:2014-08-26 Published:2014-08-26

摘要: 选用甘油和山梨醇作为塑化剂制备热塑性淀粉,并通过设计一种具有深螺槽、短螺距和长剪切区的单螺杆挤出设备,达到提高剪切效果的作用,以增强热塑性全淀粉塑料的力学性能。通过扫描电子显微镜、傅里叶红外变换光谱仪、热分析仪以及X射线衍射仪表征了增强剪切效果对单组分与复配塑化剂对全淀粉塑料塑化效果的影响。结果表明,增塑剂可以与淀粉颗粒分子形成氢键,破坏淀粉颗粒的球晶结构,使挤出成型后的热塑性淀粉能形成均一相结构;与普通的挤出工艺相比,增塑挤出制备的热塑性淀粉具有更好的热稳定性,拉伸强度提高了17.2 %,断裂伸长率降低了18 %。

Abstract: Thermoplastic starch plastics was prepared by using glycerol and sorbitol as plasticizers,and a single screw extrusion equipment with deep screw grooves, short pitch, and long shear zone was designed to enhance shear action and improve the mechanical properties of thermoplastic fullstarch plastics. The effects of strong shearing on the fullstarch plastics using scanning electron microscopy, infrared spectroscopy, thermal analysis, and Xray diffraction. It showed that the hydrogen bonds were formed between plasticizer and starch granules, the spherulite structure of the starch granule was destroyed, which made the starch form a homogeneous phase structure after extrusion. Compared with normal extrusion process, the material at break extruded by the newly designed extruder gave a better thermal stability, moreover, the tensile strength increased by 172 %, and the elongation at break decreased by 18 %.