中国塑料 ›› 2015, Vol. 29 ›› Issue (02): 32-38.DOI: 10.19491/j.issn.1001-9278.2015.02.006

• 材料与性能 • 上一篇    下一篇

PBT/PP/POE-g-GMA共混体系结晶及流变性能的研究

孟东伟1,陈庆华2,夏新曙3,陈振树钱庆荣2,黄宝铨2,肖荔人1   

  1. 1. 福建师范大学2. 福建师大环境科学与工程学院3. 福建省污染控制与资源循环利用重点实验室
  • 收稿日期:2014-10-08 修回日期:2014-11-15 出版日期:2015-02-26 发布日期:2015-02-26

Study on Crystallization and Rheological Behaviors of PBT/PP/POE-g-GMA Blends

  • Received:2014-10-08 Revised:2014-11-15 Online:2015-02-26 Published:2015-02-26

摘要: 摘要:本文以聚乙烯辛烯接枝甲基丙烯酸缩水甘油酯(POE-g-GMA)为相容剂,采用转矩流变熔融塑化制备聚对苯二甲酸丁二醇酯(PBT)/聚丙烯(PP)共混材料,通过扫描电镜(SEM)、旋转流变仪、差示扫描量热仪(DSC)和偏光显微镜(POM)等分析手段进行表征。结果表明:在PBT/PP共混体系中引入POE-g-GMA后,(1)共混体系中分散相的粒径减小,两相界面模糊;(2)体系中出现了具有更长松弛时间的新的大分子链,使体系黏度随之增大,最终形成了“类凝胶网络”结构;(3)共混体系的结晶性能具有组分依赖性。

Abstract: Abstract: The poly(butylenes terephthalate)/(propylene)(PBT/PP) blends compatibilized by poly(ethylene-octene) (POE-g-GMA) grafted glycidyl methacrylate were prepared by melting using torque rheometer and were characterized by scanning electron microscope(SEM), dynamic rheological testing, differential scanning calorimeter(DSC) and polarizing microscope(POM), respectively. It was clear that the introduction of POE-g-GMA into PBT/PP blends results in, (1) the size of particles in the PBT/PP system decreased and the interface between phases became obscured, (2) new macromolecular chains with a prolonged the relaxation time formed, which increased the system viscosity and finally created a kind of gel network structure, (3) the crystalline property of the PBT/PP blends showed component-dependence.