中国塑料 ›› 2015, Vol. 29 ›› Issue (02): 49-52.DOI: 10.19491/j.issn.1001-9278.2015.02.009

• 材料与性能 • 上一篇    下一篇

全生物降解PLA/PBC薄膜的制备及性能研究

顾晓华,宋雪,曾鹏,张希伟,程伟东   

  1. 齐齐哈尔大学
  • 收稿日期:2014-10-08 修回日期:2015-01-23 出版日期:2015-02-26 发布日期:2015-02-26

Preparation and Performance Research of the PBC-PLA Biodegradable Film

  • Received:2014-10-08 Revised:2015-01-23 Online:2015-02-26 Published:2015-02-26

摘要: 本文以PBC(聚碳酸丁二醇酯)和PLA(聚乳酸)为主要原料,经双螺杆挤出机混合制得吹膜专用树脂,然后通过吹膜机制备出PBC/PLA全生物降解薄膜。并对全生物降解薄膜做了力学性能测试、差示扫描量热分析(DSC)、热重分析(TG)、酶降解性能和扫描电镜(SEM)分析。结果表明PBC/PLA全生物降解材料具有很好的相容性,随着PBC含量的增加,多组分PBC/PLA生物降解薄膜的降解性能逐渐提高。薄膜具有良好的热稳定性。PBC/PLA全生物降解薄膜拉伸强度随PBC含量增加有所降低但与PLA相比强度的降低不超过19.5%,薄膜的断裂伸长率确能由6.63%提高到192.50%,大大的提升了PLA的韧性。

Abstract: PLA ( Polylactic acid ) as the main raw material were blown special resin mixture obtained by twin-screw extruder, and then we blew out of the PBC / PLA multi-component film on film blowing machine. To study the tensile testing and the processing performance we could conclude that when the mass ratio of PLA: PBC: citrate : erucic acid amide: antioxidant (1010) : chain extender agent was equal to 100:20:10:2:0.2:0.5, the processing performance and the mechanical properties are good, and the tensile strength reached to 58.50 MPa, elongation at break reached up to 192.50% , it greatly enhanced the toughness of the PLA; It was found by enzymatic degradation experiment, the degradation of the multicomponent biodegradable films of PBC/PLA gradually increased with the increase of the content of PBC but it didn’t increase too much comparing with the pure PLA.