中国塑料 ›› 2015, Vol. 29 ›› Issue (02): 84-89 .DOI: 10.19491/j.issn.1001-9278.2015.02.016

• 加工与应用 • 上一篇    下一篇

热处理条件对聚丙烯流延基膜取向片晶结构及拉伸成孔性的影响

俞克非   

  1. 常州机电职业技术学院
  • 收稿日期:2014-06-23 修回日期:2015-02-04 出版日期:2015-02-26 发布日期:2015-02-26

Effects of annealing conditions on oriented lamellar structures of PP cast precursor and microporous membrane formation by uniaxially stretching

  • Received:2014-06-23 Revised:2015-02-04 Online:2015-02-26 Published:2015-02-26

摘要: 摘要:为了优化挤出流延单向拉伸法制备聚丙烯微孔膜的工艺,以温度、时间和基膜受到的张应力做为热处理条件变量,通过DSC、FTIR、SEM、电子材料试验机和透气率测试仪等方法表征流延基膜的取向片晶结构参数和微孔膜的孔结构,考察热处理条件对聚丙烯流延基膜取向片晶结构和拉伸成孔性的影响。研究表明,随热处理温度从120℃提高到145℃,基膜的取向片晶结构得到改善,硬弹性增强,拉伸成孔性能变好;随热处理时间延长,基膜的结晶度、片晶厚度及取向程度不断提高,取向片晶结构趋于完善,当热处理时间达到30min后,取向片晶结构的完善程度接近稳定;在热处理过程中对基膜施加适当张应力可以提高基膜的片晶取向程度和硬弹性,改善其拉伸成孔性。

Abstract: Abstract: The effects of annealing temperature, annealing time and tensile stress applying to precursors during the annealing process on the oriented lamellar structures of PP cast precursors and micropore-forming performance by uniaxially stretching were investigated. Crystallinity, lamellar thickness, lamellar crystalline orientation and elastic recovery of PP casting precursors were characterized by DSC, FT-IR, SEM and electronic mechanical tester. Microporous structure was evaluated with porosity and Gurley value. It was found that the oriented lamellar structure of PP casting precursor was gradually improved as the annealing temperature increased from 120℃ to 145℃, leading to an higher elastic recovery value of PP casting precursor and better micropore-forming performance by uniaxially stretching. Further raising annealing temperature, however, would damage the oriented lamellar structure of PP casting precursor, giving rise to lower levels of porosity and permeability after uniaxially stretching. By prolonging annealing time at 145℃, crystallinity, lamellar thickness, lamellar crystalline orientation and elastic recovery of PP casting precursors kept increase at first, and leveled off after 30 min. Applying moderate tensile stress to precursor film during annealing process could increase lamellar crystalline orientation and elastic recovery value of the film, resulting in better micropore-forming performance.