中国塑料 ›› 2016, Vol. 30 ›› Issue (10): 81-85 .DOI: 10.19491/j.issn.1001-9278.2016.10.015

• 助剂 • 上一篇    下一篇

聚硅酸/聚丙烯酰胺复合絮凝剂的研究

张永明,邹静,苗宗成,赵阳   

  1. 西京学院
  • 收稿日期:2016-07-11 修回日期:2016-08-24 出版日期:2016-10-26 发布日期:2016-10-26

Poly(silicic acid)/Polyacrylamide Composite Flocculant for Oil-containing Waste Water Treatment

  • Received:2016-07-11 Revised:2016-08-24 Online:2016-10-26 Published:2016-10-26
  • Contact: Yong-Ming Zhang

摘要: 以硅酸钠为前驱体,制备得到硅溶胶,然后采用原位聚合法一步合成了聚硅酸/聚丙烯酰胺复合絮凝剂,通过红外光谱对合成产物的结构进行了表征。采用透光率、化学需氧量去除率对絮凝剂的絮凝效果进行了表征,并探讨了聚硅酸pH值、老化时间、聚合反应温度和时间等合成条件对絮凝效果的影响。结果表明,当硅酸钠浓度为0.5 mol/L、聚硅酸pH=5、老化时间为24 h、丙烯酰胺为5 g、引发剂用量为0.3 g,聚合反应温度为70 ℃、时间为90 min时,得到的聚硅酸/聚丙烯酰胺絮凝剂的絮凝效果最佳。

关键词: 聚丙烯酰胺, 聚硅酸, 复合絮凝剂, 石油废水

Abstract: Silica sol was prepared by using sodium silicate as a precursor, and then the poly(silicic acid)/polyacrylamide composite flocculant was synthesized through in-situ polymerization. The chemical structure of the composite flocculant was characterized by Fourier-transform infrared spectroscopy (FTIR). The effects of pH value, reaction time and temperature on flocculation effectiveness were investigated by light transmittance and removal ratio for the oil-containing waste water. It was found that the composite flocculant exhibited the best flocculation performance when the synthetic conditions were set to the sodium silicate concentration of 0.5 mol/L, the acrylamide amount of 5.0 g, the initiator amount of 0.3 g, the poly(silicic acid) acidity of pH=5, the reaction time of 90 min, the aging time of 24 h, and the temperature of 70 ℃.

Key words: polyacrylamide, poly(silicic acid), composite flocculant, oil-containing waste water