中国塑料 ›› 2017, Vol. 31 ›› Issue (1): 55-59 .DOI: 10.19491/j.issn.1001-9278.2017.01.010

• 材料与性能 • 上一篇    下一篇

环氧树脂包覆MPP阻燃EVA的研究

姚培,李树白,刘洋   

  1. 常州工程职业技术学院
  • 收稿日期:2016-09-21 修回日期:2016-10-21 出版日期:2017-01-26 发布日期:2017-01-26

Study on Encapsulation of Melamine Pyrophosphate with Epoxy Resin as Flame Retardant for EVA

  • Received:2016-09-21 Revised:2016-10-21 Online:2017-01-26 Published:2017-01-26
  • Contact: Pei Yao

摘要: 通过原位聚合法制备了以环氧树脂(EP)为壁材,三聚氰胺聚磷酸盐(MPP)为芯材的环氧包覆三聚氰胺聚磷酸盐(EPMPP),将其与二乙基次磷酸铝(ADP)复配后制备了阻燃乙烯醋酸乙烯酯共聚物(EVA)复合材料,并对阻燃材料材料进行了极限氧指数、UL 94垂直燃烧测试以及热失重分析表征。结果表明,当ADP与EPMPP质量比为2∶1、添加量为40 %(质量分数,下同)时,阻燃复合材料的极限氧指数达到最高值31 %,UL 94垂直燃烧测试达V-0级;EVA/ADP/EPMPP阻燃复合材料的初始分解温度为303 ℃,850 ℃时残炭量为18 %,较EVA/ADP/MPP阻燃复合材料有较大幅度的提高。

Abstract: A flameretardant (EPMPP) based on a melamine pyrophosphate (MPP) core and epoxy shell were prepared through an insitu polymerization reaction at a reaction temperature of 75 ℃ with curing time of 4 h, and its morphology and microstructure were characterized by scanning electron microscopy, Fouriertransform infrared spectroscopy and water contact angle. The results confirmed that MPP particles were successfully encapsulated by epoxy resin. The flameretarded poly (ethylene-co-vinyl acetate) (EVA) composites were fabricated by a combination of EPMPP with aluminium diethylphosphinate (ADP) as an intumescent flameretardant system, and their flameretardant properties were investigated by limiting oxygen index, vertical burning experiment and thermogravimetric analysis. The results indicated that the composites achieved a UL 94 V-0 classification and an oxygen index value of 31 % when the intumescent flame retardant system was incorporated into EVA at a weight fraction of 40 % with an ADP/EPMPP mass ratio of 2/1. In addition, the composites exhibited an initial decomposition temperature of 303 ℃ and a char yield of 18 %.