中国塑料 ›› 2017, Vol. 31 ›› Issue (9): 120-126.DOI: 10.19491/j.issn.1001-9278.2017.09.019

• 助剂 • 上一篇    下一篇

HM-828在聚氯乙烯电缆料中的增塑效果

林娟1,温变英1,邓健能2,胡倩君2   

  1. 1. 北京工商大学
    2. 南通海珥玛科技股份有限公司
  • 收稿日期:2017-05-13 修回日期:2017-06-12 出版日期:2017-09-26 发布日期:2017-10-25
  • 基金资助:
    北京工商大学高分子功能薄膜创新团队资助项目

Plasticizing Effect of HM-828 on Poly(vinyl chloride) Cable Materials

  • Received:2017-05-13 Revised:2017-06-12 Online:2017-09-26 Published:2017-10-25

摘要: 通过熔融共混法制备了聚氯乙烯(PVC)电缆料,研究了新型环保增塑剂二乙酰环氧植物油甘油酯(HM-828)对PVC的增塑效果及其增塑机理。结果表明,HM-828对PVC树脂具有良好的增塑作用,加入50份(质量份,下同)的HM-828可使PVC树脂的玻璃化转变温度(Tg)由80 ℃降低到-20 ℃;加入35~50份的HM-828,PVC电缆料热老化前后的力学性能、热稳定性、电绝缘性等各项指标均达到GB/T 8815—2008标准的要求,且耐溶剂抽提性,高低温析出性能优良。

Abstract: In this paper, poly(vinyl chloride) (PVC) cable materials were prepared by melt blending, and plasticizing effect of a plant-based plasticizer, Diacetyl epoxidized vegetable-oil acids glyceride (HM-828), on PVC was investigated, and its plasticizing mechanisms were studied.The results indicated that HM-828 exhibited a high plasticizing efficiency for PVC, and it significantly reduced the glass transition temperature of PVC from 80 to-20 ℃ at a loading of 50 phr.Incorporation of 35~50 phr HM-828 into PVC could make mechanical properties, thermal stability and electrical resistance meet the reguirements of national standard of GB/T 8815—2008. The resulting PVC compounds also achieved a significant enhancement in solvent extraction resistance and precipitation resistance at both a high and low temperature.