中国塑料 ›› 2018, Vol. 32 ›› Issue (03): 85-91.DOI: 10.19491/j.issn.1001-9278.2018.03.014

• 加工与应用 • 上一篇    下一篇

PBS/PLA/滑石粉3D打印线材制备及熔融沉积成型工艺研究

周运宏1,夏新曙2,杨松伟1,黄宝铨1,陈庆华3,肖荔人1   

  1. 1. 福建师范大学
    2. 福建省污染控制与资源循环利用重点实验室
    3. 福建师大环境科学与工程学院
  • 收稿日期:2017-10-20 修回日期:2017-11-17 出版日期:2018-03-26 发布日期:2018-04-26
  • 基金资助:
    国家重点研发计划项目

Study on Preparation and Fused Deposition Modeling Technology of PBS/PLA/Talc Filament for 3D Printing

  • Received:2017-10-20 Revised:2017-11-17 Online:2018-03-26 Published:2018-04-26

摘要: 以聚丁二酸丁二醇酯(PBS)为基体,滑石粉和聚乳酸(PLA)为改性剂,采用熔融挤出法制备了PBS/PLA/滑石粉三维 (3D)打印线材,并对其进行了熔融成型研究。通过分析结晶性能、流变性能、力学性能、断面形貌和打印效果对PBS/PLA/滑石粉体系进行了探究。结果表明,PLA的加入使PBS的结晶温度下降了5 ℃;随着PLA含量的增加,材料的复数黏度、储能模量和损耗模量均得到提高;而拉伸强度则随PLA含量的增加下降了1.71 MPa,缺口冲击强度下降了2.63 kJ/m2;PLA含量的增加使断面逐渐粗糙;在打印效果上复合材料的打印模型随PLA含量的增加而变得美观规整,当底板温度高于110 ℃时,打印制件的翘曲度较低,同时拉伸强度随着打印温度的升高而增加。

Abstract: Poly(lactic acid) (PLA) and talc powder were used to modify poly(butylene succinate) (PBS), and then a PBS/PLA/talc composite filament was prepared for fused deposition modeling (FDM). The effect of PLA content on 3D printing processability was investigated by crystallinity analysis, rheological behavior, mechanical performance, scanning electron microscopy and 3D printing effect. The experimental results indicated that the crystallization temperature of PBS decreased by 5 ℃ with an increase of PLA content, but the complex viscosity and storage and loss moduli increased gradually in the presence of PLA. Moreover, with increasing PLA content, the tensile strength and notched impact strength of the composite decreased by 1.71 MPa and 2.63 kJ/m2, respectively. The fracture surface of tensile specimens also became rougher. 3D printing process parameters for PBS/PLA/talc composite filament was investigated by a FDM method. The results indicated that the printing effect was improved with the addition of PLA. The warpage was improved significantly when the plate temperature exceeded 110 ℃, and meanwhile, the tensile strength increased with an increase of printing temperature.