中国塑料 ›› 2018, Vol. 32 ›› Issue (05): 28-33.DOI: 10.19491/j.issn.1001-9278.2018.05.004

• 材料与性能 • 上一篇    下一篇

纳米二氧化硅/POE协同增韧聚对苯二甲酸乙二醇酯及其发泡行为研究

王文博,王亚桥,余科松,王向东   

  1. 北京工商大学
  • 收稿日期:2018-04-10 修回日期:2018-04-18 出版日期:2018-05-26 发布日期:2018-05-25
  • 基金资助:
    中国科学技术部;中国国家重点研究与发展计划;2017商科特色项目

Study on Synergistic Effect and Foaming Behavior of PET Toughened with Nano-SiO2/POE

  • Received:2018-04-10 Revised:2018-04-18 Online:2018-05-26 Published:2018-05-25

摘要: 通过熔融共混两步法制备了聚对苯二甲酸乙二醇酯(PET)/乙烯辛烯共聚物(POE)/纳米二氧化硅复合材料,并以超临界二氧化碳为发泡剂,采用釜压法制备了PET发泡材料。研究了纳米二氧化硅和POE对PET韧性和发泡行为的影响。结果表明,纳米二氧化硅和POE显示出协同增韧PET效应,当纳米二氧化硅含量为0.3份时,冲击强度从11.63 kJ/m2增至29.15 kJ/m2,增幅达到150 %;三元共混体系的储能模量(G′)和复数黏度(η*)随着纳米二氧化硅含量的增加而逐渐减低;随着纳米二氧化硅从零增加到1.0份(质量份,下同),PET发泡材料的泡孔尺寸从75.39 μm逐步减低至50.49 μm,泡孔密度从6.67×107 个/cm3增加到了9.61×107 个/cm3,纳米二氧化硅表现出异相成核作用。

Abstract: Poly(ethylene terephthalate) (PET)/poly(ethylene-1-octene) (POE)/nano-SiO2 composites were prepared by a two-step melt blending process and then was foamed by a batch method with supercritical carbon dioxide as a foaming agent. The effects of nano-SiO2 and POE on the toughness and foaming behaviors of composites were investigated. The results indicated that the impact resistance of composites was enhanced significantly with the addition of nano-SiO2, and the impact strength increased by 150 % from 11.63 kJ/m2 to 29.15 kJ/m2 when 0.3 phr of nano-SiO2 was introduced. There is a synergistic toughening effect observed between Nano-SiO2 and POE. The storage modulus and complex viscosity of composites were found to decrease with an increase of nano-SiO2 content. Moreover, the cell size of composite foams was reduced from 75.39 to 50.49 μm with an increase of nano-SiO2 content from 0 to 1.0 phr, but their cell density increased from 6.67×107 to 9.61×107 cells/cm3 due to the heterogeneous nucleation effect of nano-SiO2.