中国塑料 ›› 2018, Vol. 32 ›› Issue (05): 120-125.DOI: 10.19491/j.issn.1001-9278.2018.05.019

• 助剂 • 上一篇    下一篇

L-半胱氨酸改性对小麦蛋白基塑料板性能的影响研究

李萌萌1,卞科1,万小乐2,关二旗1   

  1. 1. 河南工业大学
    2. 大连市粮食局粮油检验监测站
  • 收稿日期:2017-11-21 修回日期:2017-12-07 出版日期:2018-05-26 发布日期:2018-05-25
  • 基金资助:
    豆粕基绿色木材胶黏剂的创制;超声波联合化学改性大豆蛋白基木材胶黏剂的研究;国家现代农业(小麦)产业技术体系建设专项

Effect of L-cysteine modification on properties of wheat-gluten based bioplastics

  • Received:2017-11-21 Revised:2017-12-07 Online:2018-05-26 Published:2018-05-25

摘要: 以小麦蛋白(谷朊粉)为原料,采用L-半胱氨酸对其改性制备植物蛋白基塑料板,考察了L-半胱氨酸添加量、改性温度和改性时间对小麦蛋白基塑料板性能的影响,并通过正交试验确定了L-半胱氨酸改性的最佳工艺条件。结果表明,若优先考虑拉伸强度,最佳工艺条件为L-半胱氨酸添加量6 %,改性温度40 ℃,改性时间50 min,塑料板的拉伸强度为37.68 MPa,断裂伸长率为22.83 %,吸水率为76.08 %;若以断裂伸长率为主要考察指标,最佳工艺条件为L-半胱氨酸添加量4 %,改性温度30 ℃,改性时间30 min,塑料板的拉伸强度为13.24 MPa,断裂伸长率为80.19 %,吸水率为80.31 %。

Abstract: The modification of wheat gluten with L-cysteine was studied to improve the properties of wheat-gluten-based bioplastics, and its effect on the properties of the resulting bioplastic panels was discussed in terms of the amount of L-cysteine, processing temperature and processing time. The optimal process conditions for the bioplastic panels were obtained from orthogonal experiments. The results indicated that the optimal modification condition was determined as an L-cysteine content of 6 wt %, a processing temperature of 40 ℃ and processing time of 50 min. The bioplastic panels obtained under this condition achieved the tensile strength of 37.68 MPa, elongation at break of 22.83 % and water absorption of 76.08 % when the tensile strength was considered as a main factor. However, if the elongation at break was taken as a main evaluation indicator, the optimum modification condition should be determined as an L-cysteine content of 4 wt %, a processing temperature of 30 ℃ and processing time of 30 min. The bioplastic panels obtained under such a condition exhibited the tensile strength of 13.24 MPa, elongation at break of 80.19 % and water absorption of 80.31 %.