中国塑料 ›› 2018, Vol. 32 ›› Issue (11): 96-101.DOI: 10.19491/j.issn.1001-9278.2018.11.016

• 加工与应用 • 上一篇    下一篇

非金属承压容器用塑料腐蚀性能变化规律研究

李茂东1,李涛2,黄国家1,李俊2,伍振凌1   

  1. 1. 广州特种承压设备检测研究院
    2. 四川理工学院机械工程学院
  • 收稿日期:2018-04-08 修回日期:2018-04-24 出版日期:2018-11-26 发布日期:2018-12-24
  • 基金资助:
    广东省质监局科技计划项目(2016CT22)

Study on Variation Law of Corrosion Behavior of Plastics Used in Non-metal Pressure Vessel

  • Received:2018-04-08 Revised:2018-04-24 Online:2018-11-26 Published:2018-12-24

摘要: 以工程应用较多的线形低密度聚乙烯(PE-LLD)和聚丙烯(PP)为研究对象,分别将2种材料的试样置于硫酸、硝酸、盐酸、氢氧化钠、氯化钠溶液中进行分组多周期腐蚀实验,并对腐蚀后的试样进行力学性能与热分析实验。结果表明,PP经10 %(质量分数,下同)的NaOH溶液腐蚀1周后,冲击强度值变化率为23.9 %;PE-LLD经10 %的HCl溶液腐蚀2周后,冲击强度变化率达22.6 %;10 %的H2SO4溶液对PE-LLD熔融热焓变化影响最为显著,经过6周浸泡腐蚀,热焓值减小率达54.4 %。

Abstract: Thermoplastics have been widely used in petroleum, chemical, construction,urban gathering and transportation systems due to their superior performance. This work focuses on the corrosive behaviors of linear low-density polyethylene (PE-LLD) and polypropylene (PP) against sulfuric acid, nitric acid, hydrochloric acid, sodium hydroxide and sodium chloride solution.The research results indicate that the impact strength of PP was found to show a loss rate of 23.9 % after corrosion ina 10 wt % NaOH solution for one week, whereas the loss rate for PE-LLD was 22.6% after corrosion in a 10 wt% HCl solution for two weeks. The effect of H2SO4 solution with a concentration of 10 wt% on the melting enthalpy of PE-LLD was very noticeable, and the enthalpy value decreased by 54.4% after immersion corrosion for 6 weeks.