中国塑料 ›› 2018, Vol. 32 ›› Issue (12): 69-74.DOI: 10.19491/j.issn.1001-9278.2018.12.011

• 材料与性能 • 上一篇    下一篇

PA6/TiO2-GO复合材料的制备及其性能研究

于翔,王晨宇,王亚飞*,王志楠,任昆仑   

  1. 河南工程学院材料与化学工程学院
  • 收稿日期:2018-05-20 修回日期:2018-07-05 出版日期:2018-12-26 发布日期:2019-01-25
  • 基金资助:
    自然科学基金青年基金项目(51608175);河南省科技厅科技攻关项目

Study on Preparation and Properties of PA6/TiO2-GO Composites

  • Received:2018-05-20 Revised:2018-07-05 Online:2018-12-26 Published:2019-01-25

摘要: 近年来,环境污染问题越来越严重,光催化技术在处理污水和净化空气等方面发挥着重要的作用。本文通过差示扫描量热仪、电子万能拉伸试验机、可见分光光度计等仪器,主要研究不同纳米TiO2用量对PA6/TiO2-GO复合材料的热学性能、力学性能、光催化性能等的影响。通过研究发现:随纳米TiO2含量的增加,PA6/TiO2-GO复合材料的熔点逐渐降低,结晶度先增大后减小(复合材料的结晶度均大于纯PA6的结晶度);断裂强度逐渐减小,断裂伸长率逐渐增大;纳米TiO2对亚甲基蓝溶液的光催化降解能力越来越强。在相同纳米TiO2含量下,加入GO后能有效提高TiO2的光催化降解能力,光催化降解能力能提高10%左右。

Abstract: In recent years, the problem of environmental pollution have become more and more serious. Photocatalytic technology plays an important role in treating sewage and purifying air. In this paper, the effect of different nano-TiO2 dosage on the thermal properties, mechanical properties, photocatalytic properties of PA6/TiO2-GO composite were studied by the differential scanning calorimeter, electronic universal tensile testing machine, visible spectrophotometer and other instruments. The results of the study show that: with the increase of nano-TiO2 content, the melting point of PA6/TiO2-GO composites gradually decreases, the crystallinity increases first and then decreases (the crystallinity of composites is greater than that of pure PA6). The breaking strength gradually decreases. The elongation at break gradually increases. The ability of nano-TiO2 to photocatalytic degradation of methylene blue solution becomes stronger and stronger. At the same TiO2 content, adding GO can effectively improve the photocatalytic degradation of TiO2, and the photocatalytic degradation capability can be improved by about 10%.