中国塑料 ›› 2019, Vol. 33 ›› Issue (4): 12-16.DOI: 10.19491/j.issn.1001-9278.2019.04.003

• 材料与性能 • 上一篇    下一篇

马来酸酐表面改性秸秆增强热塑性淀粉复合材料

银鹏,郭露露,曹联君,李金龙,郭斌   

  1. 南京林业大学理学院化学与材料科学系
  • 收稿日期:2018-11-02 修回日期:2018-12-03 出版日期:2019-04-26 发布日期:2019-04-26

Study on maleic anhydride-treated straw-reinforced thermoplastic starch composites

  • Received:2018-11-02 Revised:2018-12-03 Online:2019-04-26 Published:2019-04-26

摘要: 首先用马来酸酐(MA)对小麦秸秆(WS)表面进行预处理,再经双螺杆挤出机在高温剪切作用下与玉米淀粉及增塑剂共混制备马来酸酐改性秸秆增强热塑性淀粉(MA-WS/TPS)复合材料,研究了MA的用量对MA-WS/TPS的力学性能,断面形貌,热稳定性和耐水性的影响。结果表明,WS经不同用量的MA改性后, 以1wt% 添加于MA-WS/TPS中,使复合材料的性能改善明显。当MA用量为4wt%时,其拉伸强度和断裂伸长率达到最佳(2.76MPa和158.24%);热稳定性方面,MA改性使WS/TPS复合材料的最大热分解速率有所提高;此外,接触角结果表明, MA处理使得复合材料的耐水性显著提高,当MA用量为6wt%时,接触角可达到83.6°。综合性能以MA含量4wt%制得的复合材料最优。

Abstract: In this work, wheat-straw (WS) was surface-treated with maleic anhydride (MA) and then melt blended with corn starch to prepare the MA-treated WS-reinforced thermoplastic starch composites. The effects of MA content on the mechanical properties, thermal stability, morphology and water resistance of the composites were investigated. The results indicated that the mechanical properties of the composites were improved at the WS content of 1 wt.% and the MA content of 4 wt.%. The composite also achieved the tensile strength of 2.76 MPa and the elongation at break of 158.24%. As for the thermal stability, the incorporation of MA-treated WS improved the maximum decomposition rate of the composites. Moreover, the composites showed a water contact angle of 83.6° at the MA content of 6 wt.%. The optimal content MA was determined as 4 wt.% for the composites on the basis of the investigation results.