中国塑料 ›› 2019, Vol. 33 ›› Issue (6): 8-11.DOI: 10.19491/j.issn.1001-9278.2019.06.002

• 材料与性能 • 上一篇    下一篇

四溴双酚A(2,3二溴丙基)醚阻燃聚丙烯材料低温韧性研究

姜向新,杨霄云,杨友强   

  1. 金发科技股份有限公司
  • 收稿日期:2019-02-12 修回日期:2019-05-28 出版日期:2019-06-26 发布日期:2019-07-26

Study on Low-temperature Toughness of Polypropylene Flame Retardant with BDDP

  • Received:2019-02-12 Revised:2019-05-28 Online:2019-06-26 Published:2019-07-26

摘要: 分别以均聚和共聚聚丙烯(PP)为基体树脂,四溴双酚A(2,3二溴丙基)醚(BDDP)为阻燃剂,制备了一系列阻燃改性PP复合材料,考察了不同均聚和共聚PP及BDDP含量对阻燃改性PP的低温缺口和无缺口冲击性能的影响。结果表明,当BDDP阻燃剂含量为15 %(质量分数,下同),温度为-10 ℃时,以共聚PP为基材的BDDP阻燃改性材料冲击性能比均聚PP保持的好;EP300M牌号的共聚PP树脂随着BDDP阻燃剂含量从3 %增加到15 %,低温冲击性能下降明显;温度对BDPP阻燃PP材料的冲击性能影响较大。

Abstract: The article reported an investigation on the effects of resin type, content of benzene-1,(1-methyl-eehylidene)bis[(3,-5di-bromo)-4-(2,3-dibrono-propoxy)] (BDDP) and temperature on the notched and non-notched impact toughness of flame retardant polypropylene (PP)under the low-temperature condition. The results indicated that the homopolymerization-type flame retardant PP exhibited better impact resistance than the copolymerization-type one at -10 ℃ when 15 wt% of BDDP was incorporated. As for the copolymerization-type PP with a commercial grade of EP300M, its low-temperature impact toughness dropped significantly when the content of BDDP was improved from 3 wt% to 15 wt%. This result suggested that there was a great effect of temperature on impact toughness of the flame retardant PP with DBBP.