中国塑料 ›› 2019, Vol. 33 ›› Issue (9): 46-49.DOI: 10.19491/j.issn.1001-9278.2019.09.008

• 材料与性能 • 上一篇    下一篇

智能卡制备中PETG预涂膜的性能研究

周建石,林崇   

  1. 江苏华信新材料股份有限公司
  • 收稿日期:2019-05-04 修回日期:2019-05-23 出版日期:2019-09-26 发布日期:2019-10-25

Study on Performance of PETG Pre-coating Film for Preparation of Smart Card

ZHOU Jianshi, LIN Chong   

  1. Jiangsu Huaxin New Material Co,Ltd
  • Received:2019-05-04 Revised:2019-05-23 Online:2019-09-26 Published:2019-10-25
  • Contact: Jian-Shi ZHOU E-mail:zhoujianshi2008@163.com

摘要: 以六亚甲基二异氰酸酯(HDI)、聚碳酸酯二醇(PCDL)、聚四氢呋喃二醇(PTMG)、甲基丙烯酸β羟乙酯(HEMA)、二羟甲基丙酸(DMPA,2,2二羟甲基丙酸)等为基本原料,制备出聚对苯二甲酸乙二醇酯1,4环己烷二甲醇酯(PETG)预涂膜用涂层。利用红外光谱仪和扫描电子显微镜等测试设备对预涂膜进行表征,并研究了涂层中不同原料对PETG预涂膜热覆合性能的影响。结果表明,使用水合肼后扩链,增加聚醚二醇和丙烯酸酯的量,PETG预涂膜活化温度更低,剥离强度最优。

关键词: 智能卡, PETG预涂膜, 热覆合

Abstract: Poly(ethylene terephthalate-co-1,4-cylclohexylenedimethylene terephthalate) (PETG) pre-coating films were prepared by using hexamethylene diisocyanate (HDI), polycarbonate diol (PCDL), polytetrahydrofuran diol (PTMG), methacrylic acid-β-hydroxyethyl (HEMA), and dimethylol propionic acid as raw materials. The chemical structure of pre-coating films were characterized by infrared spectroscopy and scanning electron microscopy, and the effect of raw materials on the thermal cladding properties of pre-coated films were investigated. The results indicated that the activation temperature of pre-coated films became lower when the amounts of polyether diol and acrylate increased and hydrazine hydrate was used, resulting in optimum peeling strength.

Key words: smart cardpoly(ethylene terephthalateco-1,4-cylclohexylenedimethylene tereph- thalate), precoating film, thermal cladding

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