快速高吸有机溶剂树脂制备及其性能研究

doi:10.19491/j.issn.1001-9278.2019.12.001

中国塑料 ›› 2019, Vol. 33 ›› Issue (12): 1-6.DOI: 10.19491/j.issn.1001-9278.2019.12.001

• 材料与性能 • 下一篇

快速高吸有机溶剂树脂制备及其性能研究

耿孝岭¹，张智嘉¹，王国军¹，李万利^2*

1. 教育部超轻材料和表面技术重点实验室，哈尔滨工程大学材料科学与化学工程学院
2. 军事科学院系统工程研究院

收稿日期:2019-07-23 修回日期:2019-08-23 出版日期:2019-12-26 发布日期:2020-01-17

Preparation and Properties of Organic Solvent-absorption Resin with Rapid Rate and High Capacity

GENG Xiaoling¹， ZHANG Zhijia¹, WANG Guojun¹， LI Wanli^2*

1.Key Laboratory of Superlight Material and Surface Technology of Ministry of Education, College
of Material Science and Chemical Engineering, Harbin Engineering University 2. Institute of Systems Engineering, Academy of Military Sciences

Received:2019-07-23 Revised:2019-08-23 Online:2019-12-26 Published:2020-01-17

摘要/Abstract

摘要： 采用悬浮聚合的方法，以甲基丙烯酸十八烷基酯、丙烯酸丁酯、苯乙烯为单体制备了三元高吸有机溶剂树脂，并探索了交联剂用量对三元高吸有机溶剂树脂的饱和吸附率的影响。结果表明，采用位阻小的1,4丁二醇二甲基丙烯酸酯为交联剂，当交联剂用量为单体总质量的0.25 %时，树脂的饱和吸附率最高；树脂对甲苯、氯仿、正己烷、二氯甲烷的吸附在15 min内均达到饱和状态，饱和吸附率分别为23.18、34.00、15.86、22.20 g/g，说明所制备的三元高吸有机溶剂树脂具有优异的吸有机溶剂性能。

Abstract: An absorption resin with a high capacity for four organic solvents was prepared by suspension polymerization using octadecyl methacrylate, butyl acrylate and styrene as monomers, and the effect of crosslinker content on the saturated adsorption rate of the synthesized absorption resin was investigated. The experimental results indicated that the absorption resin achieved a maximum saturated adsorption rate at the crosslinker content of 0.25 wt%, and it presented a saturated adsorption time within 15 min for toluene, chloroform, n-hexane, and dichloromethane. The absorption resin presented the saturated adsorption rates of 23.18, 34.00, 15.86 and 22.20 g/g for toluene, chloroform, n-hexane and dichloromethane, respectively. The absorption resin exhibited excellent absorption performance.

耿孝岭, 张智嘉, 王国军, 李万利. 快速高吸有机溶剂树脂制备及其性能研究[J]. 中国塑料, 2019, 33(12): 1-6.

GENG Xiaoling, ZHANG Zhijia, WANG Guojun, LI Wanli. Preparation and Properties of Organic Solvent-absorption Resin with Rapid Rate and High Capacity [J]. China Plastics, 2019, 33(12): 1-6.

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快速高吸有机溶剂树脂制备及其性能研究

Preparation and Properties of Organic Solvent-absorption Resin with Rapid Rate and High Capacity

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