中国塑料 ›› 2019, Vol. 33 ›› Issue (12): 11-15,68.DOI: 10.19491/j.issn.1001-9278.2019.12.003

• 材料与性能 • 上一篇    下一篇

石墨烯增强聚丙烯/高密度聚乙烯纤维研究

武卫莉1,2,李响1   

  1. 1.齐齐哈尔大学 材料科学与工程学院 2.黑龙江省高校聚合物复合改性重点实验室
  • 收稿日期:2019-08-14 修回日期:2019-08-30 出版日期:2019-12-26 发布日期:2020-01-17
  • 基金资助:
    黑龙江省省属高等学校基本科研业务费科研基金

Graphene-Reinforced Polypropylene/High-density Polyethylene Composite Fibers

WU Weili1,2,LI Xiang1   

  1. 1.College of Materials Science and Engineering, Qiqihar University 2.Key Laboratory of Polymer Composition and Modification, College of Heilongjiang Province
  • Received:2019-08-14 Revised:2019-08-30 Online:2019-12-26 Published:2020-01-17

摘要: 针对聚丙烯(PP)纤维拉伸强度不够高和刚性差的缺点,采用高密度聚乙烯(PE-HD)及石墨烯通过熔融法制备PP/PE-HD/石墨烯纤维;通过偏光显微镜、拉伸强度、扫描电子显微镜、差式扫描量热仪、傅里叶红外光谱仪等测试研究了石墨烯加入对PP/PE-HD纤维性能的影响。结果表明,当加入25份(质量份数,下同)PE-HD,改性纤维的拉伸强度达2.46 GPa,与PP纤维的拉伸强度相比提升了8 %;当继续加入0.3份石墨烯时, PP/PE-HD/石墨烯纤维的拉伸强度比PP/PE-HD纤维提高了1.6 %;加入PE-HD和石墨烯改性后,PP纤维的热稳定性改善。

Abstract: In view of the faults of polypropylene (PP)fiber like insufficient tensile strength and low rigidity, the PP/high-density polyethylene (PE-HD)/graphene composite fibers were prepared by a melt-spinning method, and the effect of graphene on their properties was investigated by polarizing microscope, tensile experiment, scanning electron microscope, differential scanning calorimeter and Fourier-infrared spectrometer. The results indicated that the tensile strength of the composite fibers reached 2.46 GPa at the PE-HD content of 25 phr, which increased by 8 % compared to pure PP fiber. When 0.3 phr of graphene were incorporated, the composite fibers gained an increase in tensile strength by 1.6 % compared to the pristine PP/PE-HD fiber. The thermal stability of the fibers was also improved with the addition of PE-HD and graphene.