不同层板离子及插层类水滑石对PVC热稳定性的影响

doi:10.19491/j.issn.1001-9278.2020.02.012

中国塑料 ›› 2020, Vol. 34 ›› Issue (2): 74-78.DOI: 10.19491/j.issn.1001-9278.2020.02.012

不同层板离子及插层类水滑石对PVC热稳定性的影响

张宁¹,李先铭¹,张红霞¹,王秀阁¹,于静²

1. 唐山师范学院
2. 唐山师范学院化学系,唐山市绿色专用化学品重点实验室

收稿日期:2019-09-23 修回日期:2019-10-24 出版日期:2020-02-26 发布日期:2020-02-26

Effect of Intercalated Hydrotalcite-like Compounds with Different Interlayer Ions on Thermal Stability of PVC

Received:2019-09-23 Revised:2019-10-24 Online:2020-02-26 Published:2020-02-26

摘要/Abstract

摘要： 分别合成了不同层板离子、不同价态无机酸根及有机酸根插层、不同直链链长插层类水滑石，采用热老化烘箱法、刚果红法、转矩流变仪探究了对聚氯乙烯(PVC)热稳定性能的影响。结果表明，类水滑石层板中引入稀土元素及增加离子的数目可提高PVC的热稳定性；不同价态无机酸根及有机酸根插层类水滑石中，二价酸根插层的类水滑石均表现出最佳的热稳定性能；类水滑石插层中随着有机酸碳链的不断增长，热稳定性出现了先增强后降低的趋势。

Abstract: A series of hydrotalcite-like compounds were synthesized, and these compounds had different interlayer ions and various intercalations with different valence inorganic acid radicals and different chain-length organic acid radicals. The effect of the hydrotalcite-like compounds on the thermal stability of PVC were investigated by means of thermal aging oven method, Congo red method and torque rheometer. The results indicated that the thermal stability of PVC was improved by incorporating the rare-earth elements and increasing the quantity of ions in the interlay of the compounds. For the hydrotalcite-like compounds with different valence inorganic acid radicals and organic acid radicals, the compounds intercalated with bivalent acid radicals exhibited the best thermal stability. Moreover, the thermal stability showed an increasing trend at first and then tended to decrease with an increase of the carbon-chain length of organic acids in the hydrotalcite-like intercalation.

张宁李先铭张红霞王秀阁于静. 不同层板离子及插层类水滑石对PVC热稳定性的影响[J]. 中国塑料, 2020, 34(2): 74-78.

参考文献

[1]蔺道雷, 田国峰, 武德珍. 水滑石的制备及应用进展[J].中国塑料, 2016, 30 (11) : 8-12
Lin Daolei, Tian Guofeng, Wu Dezhen. Application of hydrotalcite in soft poly(vinyl chloride) compounds [J]. China Plastics, 2016, 30(11) : 8-12
[2]张宁. 硬脂酸插层钙／锌稀土类水滑石 PVC的热稳定作用[J].中国塑料, 2017, 31 (10) : 99-104.
Zhang Ning. Study on thermal stability of stearic acid intercalated Ca/Zn rare-earth hydrotalcite-like in PVC [J]. China Plastics, 2017, 31 (10) : 99-104.
[3]杨占红, 陈红燕, 温润娟, 等. 锌/铝/镧三元类水滑石的合成[J]. 塑料助剂, 2010, (6): 24-26.
Yang Zhanhong, Chen Hongyan, Wen Runjuan, et al. Preparation of Zn/Al/La-CO3-LDHs [J]. Plastics Additives, 2010, (6): 24-26.
[4] A. Bissessur, M. Naicker. Synthesis and use of hydrotalcites as heat stabilisers in thermally processed powdered polyvinylchloride (PVC) [J]. International Journal of Physical Sciences, 2013, 8(36) : 1772-1782.
[5]杨占红, 迟伟伟, 易师, 等.钙镁铝型三元类水滑石的合成及其在PVC中的应用[J]. 塑料助剂, 2008, (2) : 18-21.
Yang Zhanhong, Chi Weiwei, Yi Shi, et al. Synthesis of Ca-Mg-Al hydrotalcite-like compounds and application in PVC [J]. Plastics Additives, 2008, (2) : 18-21.
[6]王佳翰, 郎春燕, 陈小平. 水滑石类稳定剂热稳定效果的影响因素及其使用途径[J]. 中国塑料, 2015, 29(04) : 9-13.
Wang Jiahan, Lang Chunyan, Chen Xiaoping. Influencing factors thermal stability of hydrotalcite compound stabilizers and their application way as thermal stabilizers [J].China Plastics, 2015, 29(04) : 9-13.
[7] Vander Ven L, Van Gemert M L M, Batenburg Lf, et al. On the action of hydrotalcite-like clay materials as stabilizers in polyvinyl chloride [J]. Appllied Clay Science, 2000, 17(1): 25-34.
[8] Lin Y J, Wang J R, Evans D V, et al. Layer and intercalated hydrotalcite-like materials as thermal stabilizers in PVC resin [J]. Journal of Physics Chemistry Solids, 2006, 67: 998-1001.
[9]薛晓宇. 复合型插层水滑石热稳定剂制备及稳定PVC热机理研究[D]. 上海工程技术大学, 2015.
Xun Xiaoyu. Preparation of intercalated Mg/Al-LDHs and effecton thermal benhavior for poly(vinyl )chloride
[D]. Shanghai University of Engineering Science, 2015.
[10]杜宝中, 王汝敏, 邰炜, 等.有机酸阴离子/LDH复合材料的插层组装条件及热稳定性研究[J]. 材料导报, 2009, 23(24) : 27-30.
Du Baozhong, Wang Rumin, Tai Wei, et al. Intercalation assembly and thermal stability of organic acids/LDH composites [J]. Materials Reports, 2009, 23(24) : 27-30.

不同层板离子及插层类水滑石对PVC热稳定性的影响

Effect of Intercalated Hydrotalcite-like Compounds with Different Interlayer Ions on Thermal Stability of PVC

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