Abstract: PVDF/TiO2 hybrid fiber membranes were prepared by an electrospinning method, and their morphology, crystalline structure and photocatalytic performance were investigated by using SEM, XRD and visible spectrophotometer. The results indicated that there were more TiO2 particles exposed onto the surface of the hybrid fiber membranes with an increase of TiO2 content. The hybrid fiber membranes presented an increase trend in tensile strength with an increase of TiO2 content at first, and then the tensile strength tended to decrease. Their photocatalytic degradation ability was also gradually enhanced with the increase of TiO2 content. Moreover, the hybrid fiber membranes exhibited a good recyclability.