中国塑料 ›› 2014, Vol. 28 ›› Issue (08): 72-77.DOI: 10.19491/j.issn.1001-9278.2014.08.015

• 加工与应用 • 上一篇    

PS/PETG共混物的流变性能和发泡行为研究

刘本刚1,2,董帅3,王向东2,刘燕汪文昭3,杜中杰4,张晨4   

  1. 1. 北京化工大学碳纤维及功能高分子教育部重点实验室2. 北京工商大学材料与机械工程学院,轻工业塑料加工应用研究所3. 中国石油天然气管道局第五工程公司 
  • 收稿日期:2014-10-14 修回日期:2014-04-13 出版日期:2014-08-26 发布日期:2014-08-26

Rheological and Foaming Behavior of PS/PETG Blends

  • Received:2014-10-14 Revised:2014-04-13 Online:2014-08-26 Published:2014-08-26

摘要: 采用密炼机制备了聚苯乙烯(PS)和聚对苯二甲酸乙二醇酯1,4环己二甲醇酯(PETG)共混物;以超临界二氧化碳(CO2)为物理发泡剂,采用釜压法制备了PS和PS/PETG共混物发泡试样。通过旋转流变仪、扫描电子显微镜对PS和PS/PETG共混物的流变性能和泡沫的泡孔形态进行了表征。结果表明,加入PETG没有对PS的流变性能产生明显的影响,但对PS泡沫的泡孔形态影响显著,加入10 %的PETG时,其平均泡孔直径由纯PS的2268 μm降至758 μm,泡孔密度由345×108个/cm3提高到447×109个/cm3,泡孔尺寸分布明显变窄,说明PETG在PS中起到明显的气泡成核作用。

Abstract: Polystyrene and poly (ethylene terephthalate glycol) (PS/PETG)blends were prepared by an internal mixer.PS and PS/PETG foams were prepared by the batch method using supercritical CO2 as the foaming agent.The rheological properties and cellular morphology were characterized by dynamic rotational rheometer and scanning electron microscope. The results showed that the addition of PETG has no significant effect on the rheological properties of PS ,but obvious effect on the cell size morphology of PS. The average cell diameter decreased from 22.68 μm to 7.58 μm and the cell density increased from 3.45×108cell/cm3to 4.47×109cell/cm3 when adding 10 % PETG into PS. The cell distribution also became narrow. Thus PETG can serve as the nucleation agent when blended with PS.