硼化钽增强聚醚醚酮复合涂层的制备及性能评价

doi:10.19491/j.issn.1001-9278.2022.06.010

中国塑料 ›› 2022, Vol. 36 ›› Issue (6): 60-68.DOI: 10.19491/j.issn.1001-9278.2022.06.010

硼化钽增强聚醚醚酮复合涂层的制备及性能评价

黄素媛, 曹琳, 李卫, 林志丹(), 张鹏()

暨南大学先进耐磨蚀及功能材料研究院，广州 510632

收稿日期:2022-01-25 出版日期:2022-06-26 发布日期:2022-06-27
通讯作者: 林志丹（1977—），男，教授，从事高分子材料改性研究，linzd@jnu.edu.cn
张鹏（1983—），男，副研究员，从事金属生物医用材料改性研究，tzhangpeng@jnu.edu.cn
E-mail:linzd@jnu.edu.cn;tzhangpeng@jnu.edu.cn
基金资助:
国家重点研发计划项目(2018YFB2002000);广东省基础与应用基础研究基金(2021A515012271)

Preparation and performance evaluation of tantalum boride⁃reinforced polyether ether ketone composite coatings

HUANG Suyuan, CAO Lin, LI Wei, LIN Zhidan(), ZHANG Peng()

Institute of Advances Wear & Corrosion Resistant and Functional Materials，Jinan University，Guangzhou 510632，China

Received:2022-01-25 Online:2022-06-26 Published:2022-06-27
Contact: LIN Zhidan, ZHANG Peng E-mail:linzd@jnu.edu.cn;tzhangpeng@jnu.edu.cn

摘要/Abstract

摘要：

采用阴极电泳沉积技术在纯钛基板表面沉积聚醚醚酮（PEEK）/硼化钽（TaB₂）复合涂层。采用透射电子显微镜、扫描电子显微镜、X射线衍射仪和摩擦磨损试验机等方式对电泳沉积液分散性、PEEK/TaB₂复合涂层表面形貌、微观结构、结晶行为、摩擦学性能和生物学性能进行表征。结果表明，通过调节电泳沉积参数可以制备形貌均匀、具有一定厚度的PEEK/TaB₂复合涂层，在390 ℃热处理后，涂层均匀致密无孔隙；热处理可以提高PEEK/TaB₂涂层的结晶性能，TaB₂颗粒的加入使PEEK涂层获得更高的结晶度；添加较低含量的TaB₂颗粒时，复合涂层在小牛血清（fetal bovine serum，FBS）介质中表现出良好的摩擦学性能，与纯PEEK涂层相比，磨损率分别下降了48.1 %，69.1 %；但过量TaB₂颗粒在PEEK基质中出现明显的团聚现象，摩擦系数和磨损率呈现上升趋势；细胞实验表明，TaB₂良好的生物活性促进了样品表面细胞增殖。

关键词: 电泳沉积, 聚醚醚酮, 硼化钽, 摩擦学

Abstract:

PEEK/TaB₂ composite coatings were deposited on the surface of pure titanium substrates using a cathodic electrodeposition technique. Transmission electron microscopy， scanning electron microscopy， X?ray diffractometer， and friction and wear tester were used to characterize the suspension dispersion， surface morphology， microstructure， crystallinity， and tribological and biological properties of the composite coatings. The results indicated that there were a uniform morphology and a certain thickness for the composite coatings through adjusting the electrodeposition parameters. After thermal sintering at 390 ℃， the resulting coating became uniform and dense. Thermal sintering improved the crystalline properties of the PEEK/TaB₂ composite coatings， and the addition of TaB₂ particles led to a higher crystalline degree for the composite coatings. When a lower content of TaB₂ particles was added， the composite coatings showed good tribological properties in a medium of fetal bovine serum. Their wear rates decreased by 48.1 %and 69.1 %compared to the pure PEEK coating. However， there was an evident aggregation of TaB₂ particles at an excessive loading in the PEEK matrix， resulting in an increase in friction coefficient and wear rate. Cell experimental results indicated that TaB₂ had a good bioactivity to promote cell proliferation on the sample surface.

Key words: electrodeposition, polyetheretherketone, tantalum boride, tribology

中图分类号:

TQ322.4

黄素媛, 曹琳, 李卫, 林志丹, 张鹏. 硼化钽增强聚醚醚酮复合涂层的制备及性能评价[J]. 中国塑料, 2022, 36(6): 60-68.

HUANG Suyuan, CAO Lin, LI Wei, LIN Zhidan, ZHANG Peng. Preparation and performance evaluation of tantalum boride⁃reinforced polyether ether ketone composite coatings[J]. China Plastics, 2022, 36(6): 60-68.

图/表 12

图1 P?TB?3电泳沉积液中吸附了壳聚糖的TaB2和PEEK颗粒

Fig.1 TEM images of TaB2 and PEEK particles with adsorptive chitosan in P?TB?3 suspension

图2 PEEK/TaB2颗粒和PEEK颗粒沉积质量变化曲线

Fig.2 Weight variation of deposition of PEEK/TaB2 particles and PEEK particles

图3 恒定时间不同电压制备的PEEK/TaB2 涂层的宏观图

Fig.3 Macrographs of PEEK/TaB2 coatings prepared at constant time and different voltages

图4 P?TB?3涂层在15 V电压不同沉积时间下的SEM不同放大倍数形貌照片

Fig.4 SEM of different magnification topography of P?TB?3 coating at different deposition times at 15 V voltage

图5 PEEK/TaB2复合涂层在15 V， 180 s 沉积条件下的SEM形貌

Fig.5 SEM of PEEK/TaB2 composite coating at deposition conditions of 15 V， 180 s

图6 EEK粉末和PEEK/TaB2 粉末的DSC曲线

Fig.6 DSC curves for PEEK powder and PEEK/TaB2 powder

图7 P?TB?3 涂层在不同烧结温度下的SEM形貌照片

Fig.7 SEM of P?TB?3 coating at different sintering temperature

图8 390 ℃ 热处理温度下不同涂层的SEM 形貌照片

Fig.8 SEM of different coatings at 390 ℃

图9 TaB2粉末、PEEK粉末及不同涂层的XRD曲线

Fig.9 XRD patterns of TaB2 powder， PEEK powder and different coatings

图10 5 N载荷下不同涂层的摩擦因数和磨损率

Fig.10 Friction coefficient and wear rate of different coatings under 5 N load

图11 5 N载荷下不同涂层磨痕SEM形貌图

Fig.11 SEM morphology of wear scar of different coatings under 5 N load

图12 不同样品与MC3T3?E1细胞共培养后的细胞粘附和增殖情况

Fig.12 Cell adhesion and proliferation after co?culture of different samples with MC3T3?E1 cells

参考文献 31

1	PUTRA N E， MIRZAALI M J， APACHITEI I， et al. Multi⁃material additive manufacturing technologies for Ti⁃， Mg⁃， and Fe⁃based biomaterials for bone substitution ［J］. Acta Biomaterialia， 2020， 109： 1⁃20.
2	ZHANG J K， LIU J Q， WANG C T， et al. A comparative study of the osteogenic performance between the hierarchical micro/submicro⁃textured 3D⁃printed Ti6Al4V surface and the SLA surface ［J］. Bioact Mater， 2020， 5（1）： 9⁃16.
3	MA H Y， SUONAN A X， ZHOU J Y， et al. PEEK（Polyether⁃ether⁃ketone）and its composite materials in orthopedic implantation ［J］. Arab J Chem， 2021， 14（3）.
4	HALLMANN L， MEHL A， SERENO N， et al. The improvement of adhesive properties of PEEK through different pre⁃treatments ［J］. Applied Surface Science， 2012， 258（18）： 7 213⁃7 218.
5	KURTZ S M. PEEK biomaterials handbook ［M］. William Andrew， 2019.
6	ABDULLAH M R， GOHARIAN A， KADIR M R A， et al. Biomechanical and bioactivity concepts of polyetheretherketone composites for use in orthopedic implantsa review ［J］. J Biomed Mater Res Part A， 2015， 103（11）： 3 689⁃3 702.
7	OLADAPO B I， ZAHEDI S A， ISMAIL S O， et al. Recent advances in biopolymeric composite materials： Future sustainability of bone⁃implant ［J］. Renewable & Sustainable Energy Reviews， 2021， 150.
8	RIBEIRO R， INGOLE S， USTA M， et al. Tribological investigation of tantalum boride coating under dry and simulated body fluid conditions ［J］. Wear， 2007， 262（11⁃12）： 1 380⁃1 386.
9	HUNT C D， IDSO J P. Dietary boron as a physiological regulator of the normal inflammatory response： A review and current research progress ［J］. 1999， 12（3）： 221⁃233.
10	ARMSTRONG T A， SPEARS J W， LLOYD K E. Inflammatory response， growth， and thyroid hormone concentrations are affected by long⁃term boron supplementation in gilts ［J］. Journal of Animal Science， 2001， 79（6）： 1 549⁃1 556.
11	ESMAEILI M M， MAHMOODI M， IMANI R. Tantalum carbide coating on Ti⁃6Al⁃4V by electron beam physical vapor deposition method： Study of corrosion and biocompatibility behavior ［J］. International Journal of Applied Ceramic Technology， 2017， 14（3）： 374⁃382.
12	LEE S W， KIM Y W， CHEN H D. Electrical properties of Ta⁃doped SnO2 thin films prepared by the metal⁃organic chemical⁃vapor deposition method ［J］. Applied Physics Letters， 2001， 78（3）： 350⁃352.
13	LI R， LIU G， YANG L， et al. Tantalum boride as a biocompatible coating to improve osteogenesis of the bionano interface ［J］. J Biomed Mater Res Part A， 2020， 108（8）： 1 726⁃1 735.
14	KUSMIERCZYK F， ZIMOWSKI S， LUKASZCZYK A， et al. Development of Microstructure and Properties of Multicomponent MoS₂/HA/PEEK Coatings on a Titanium Alloy Via Electrophoretic Deposition and Heat Treatment ［J］. Metallurgical and Materials Transactions a⁃Physical Metallurgy and Materials Science， 2021， 52（9）： 3 880⁃3 895.
15	FIOLEK A， ZIMOWSKI S， KOPIA A， et al. Electrophoretic co⁃deposition of polyetheretherketone and graphite particles： microstructure， electrochemical corrosion resistance， and coating adhesion to a titanium alloy ［J］. Materials， 2020， 13（15）.
16	MOSKALEWICZ T， WARCABA M， CIENIEK L， et al. Hydroxyapatite/sodium alginate coatings electrophoretically deposited on titanium substrates： microstructure and properties ［J］. Applied Surface Science， 2021， 540.
17	SEUSS S， SUBHANI T， KANG M Y， et al. Electrophoretic deposition of PEEK⁃TiO₂ composite coatings on stainless steel ［J］. Electrophoretic Deposition： Fundamentals and Applications Iv， 2012， 507： 127.
18	MOSKALEWICZ T， ZIMOWSKI S， ZYCH A， et al. Electrophoretic deposition， microstructure and selected properties of composite alumina/polyetheretherketone coatings on the Ti⁃13Nb⁃13Zr alloy ［J］. Journal of the Electrochemical Society， 2018， 165（3）： D116⁃D28.
19	BESRA L， LIU M. A review on fundamentals and applications of electrophoretic deposition（EPD）［J］. Progress in Materials Science， 2007， 52（1）： 1⁃61.
20	AMMAM M. Electrophoretic deposition under modulated electric fields： a review ［J］. Rsc Advances， 2012， 2（20）： 7 633⁃7 646.
21	BASTAN F E， REHMAN M A U， AVCU Y Y， et al. Electrophoretic co⁃deposition of PEEK⁃hydroxyapatite composite coatings for biomedical applications ［J］. Colloids and Surfaces B⁃Biointerfaces， 2018， 169： 176⁃182.
22	MOSKALEWICZ T， ZYCH A， KRUK A， et al. Electrophoretic deposition and microstructure development of Si₃N₄/polyetheretherketone coatings on titanium alloy ［J］. Surface & Coatings Technology， 2018， 350： 633⁃647.
23	IVEKOVIC A， NOVAK S， LUKEK M， et al. Aqueous electrophoretic deposition of bulk polyether ether ketone（PEEK）［J］. Journal of Materials Processing Technology， 2015， 223： 58⁃64.
24	SUN F， PANG X， ZHITOMIRSKY I. Electrophoretic deposition of composite hydroxyapatite⁃chitosan⁃heparin coatings ［J］. Journal of Materials Processing Technology， 2009， 209（3）： 1 597⁃1 606.
25	MENG X， T⁃YKWON， YANG Y， et al. Effects of applied voltages on hydroxyapatite coating of titanium by electrophoretic deposition ［J］. Journal of Biomedical Materials Research Part B⁃Applied Biomaterials， 2006， 78B（2）： 373⁃377.
26	MONDRAGON⁃CORTEZ P， VARGAS⁃GUTIERREZ G. Selective deposition of hydroxyapatite nanoparticles by electrophoretic deposition ［J］. Advanced Engineering Materials， 2003， 5（11）： 812⁃815.
27	ARRIGHI V， MCEWEN I J， QIAN H， et al. The glass transition and interfacial layer in styrene⁃butadiene rubber containing silica nanofiller ［J］. Polymer， 2003， 44（20）： 6 259⁃8 266.
28	GOYAL R K， NEGI Y S， TIWARI A N. Preparation of high performance composites based on aluminum nitride/poly（ether⁃ether⁃ketone）and their properties ［J］. European Polymer Journal， 2005， 41（9）： 2 034⁃2 044.
29	GHOSH S， CHOUDHURY D， ROY T， et al. Tribological performance of the biological components of synovial fluid in artificial joint implants ［J］. Science and Technology of Advanced Materials， 2015， 16（4）.
30	HUANG S Y， CAO L， LI W， et al. Evaluation of tribological and biological properties of PEEK/TaB₂composite coatings prepared by electrodeposition ［J］. J Appl Polym Sci.
31	GHOSH S， CHOUDHURY D， DAS N S， et al. Tribological role of synovial fluid compositions on artificial joints ⁃ a systematic review of the last 10 years ［J］. Lubr Sci， 2014， 26（6）： 387⁃410.

[1]	王轲, 龙春光. PE⁃UHMW/海泡石纤维复合材料的力学性能与摩擦学性能研究[J]. 中国塑料, 2022, 36(5): 19-23.
[2]	黎帅, 龙春光, 闵建新, 周卓. 基于改性PET的极限PV值测试及摩擦学性能比较研究[J]. 中国塑料, 2021, 35(9): 87-94.
[3]	彭鑫, 龙春光, 彭鹰. PEEK/ZA8复合材料的制备及力学与摩擦学性能研究[J]. 中国塑料, 2020, 34(5): 26-31.
[4]	田仁杰, 朱光明, 吕玉伟, 吴涛涛, 任天宁, 马志亮, 张爽. 炭黑对聚醚醚酮激光吸收影响的实验研究及数值模拟[J]. 中国塑料, 2020, 34(10): 44-50.
[5]	付扬威龙春光董佩冉. 聚甲醛/海泡石纤维复合材料的制备与性能研究[J]. 中国塑料, 2019, 33(2): 24-28.
[6]	李长林黄志刚翁云宣. PEEK特种工程塑料耐磨改性研究进展及其应用展望[J]. 中国塑料, 2018, 32(04): 18-23.
[7]	刘俊鹏;龙春光;谌磊;付扬威;许可可;董佩冉. 漆籽壳纤维含量对聚甲醛/玄武岩纤维复合材料的力学及摩擦学性能的影响[J]. 中国塑料, 2017, 31(4): 40-44 .
[8]	刘焕萍;孙辉. 聚醚醚酮表面接枝O羧甲基壳聚糖及其血液相容性研究[J]. 中国塑料, 2016, 30(02): 39-42 .
[9]	王志;雷卓研;张晓玲;杨甜甜;徐艳英. 聚醚醚酮/多壁碳纳米管复合材料力学及阻燃性能研究[J]. 中国塑料, 2014, 28(11): 42-46 .
[10]	. 聚醚醚酮表面壳聚糖的固定[J]. 中国塑料, 2014, 28(06): 52-56 .
[11]	李思远;包睿莹;杨伟;冯建明杨鸣波. 聚醚醚酮共混改性研究进展[J]. 中国塑料, 2014, 28(05): 1-10 .
[12]	钱善华张翔熊福祥倪自丰李庆忠. 压力速度对PE-UHMW摩擦学性能影响的试验研究 [J]. , 2013, 27(11): 54-58.
[13]	鲜艳王宏刚任俊芳. PE-HD-g-MAH对PA66/PE-UHMW共混物力学与摩擦学行为的影响[J]. 中国塑料, 2013, 27(06): 75-80 .
[14]	史丽萍, 丁兰英, 张静, 路琴. UPR/GF/纳米Si0₂复合材料的摩擦学性能和力学性能研究[J]. 中国塑料, 2013, 27(01): 57-61.
[15]	路琴史丽萍. 基于聚甲醛及其复合材料的摩擦学研究进展[J]. 中国塑料, 2011, 25(09): 16-20 .

硼化钽增强聚醚醚酮复合涂层的制备及性能评价

Preparation and performance evaluation of tantalum boride⁃reinforced polyether ether ketone composite coatings

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 12

参考文献 31

相关文章 15

编辑推荐

Metrics

本文评价