阻燃剂DOPO-FR的合成及阻燃聚氨酯的性能研究

doi:10.19491/j.issn.1001-9278.2013.11.016

中国塑料 ›› 2013, Vol. 27 ›› Issue (11): 84-88.DOI: 10.19491/j.issn.1001-9278.2013.11.016

阻燃剂DOPO-FR的合成及阻燃聚氨酯的性能研究

张立强¹,张猛²,周永红²,胡立红²,杨晓慧²

1. 中国林业科学研究院林产化学工业研究所
2. 中国林业科学究院林产化学工业研究所

收稿日期:2013-07-23 修回日期:2013-08-21 出版日期:2013-11-26 发布日期:2013-11-26
基金资助:
国家“十二五”科技支撑计划(2012BAD32B05)

Synthesis of DOPO-FR and Performance of Flame Retardant Polyurethane Foams

Received:2013-07-23 Revised:2013-08-21 Online:2013-11-26 Published:2013-11-26

摘要/Abstract

摘要： 以苯胺、苯甲醛、9,10二氢9氧杂10磷杂菲10氧化物（DOPO）为原料合成了一种新型阻燃剂9,10二氢9氧杂10磷杂菲10氧化物4\[(苯胺)甲基\]苯（DOPOFR），并与磷酸三乙酯(TEP)、膨胀石墨(EG)复配制备了阻燃聚氨酯泡沫材料。采用红外光谱分析仪、核磁共振分析仪对DOPOFR的化学结构进行表征，并利用极限氧指数、热重分析仪等对阻燃聚氨酯泡沫材料进行性能分析。结果表明，DOPOFR质量为多元醇的20 %，聚氨酯泡沫材料的极限氧指数就可达24.7 %；DOPOFR的加入提高了聚氨酯泡沫的力学性能和热稳定性；EG、TEP、DOPOFR三者协同阻燃可使聚氨酯泡沫的极限氧指数达到32 %。

Abstract: A novel flame retardant for polyurethane foam, DOPOFR was synthesized by the condensation of benzaldehyde with aniline and DOPO. Using above flame retardant and expandable graphite (EG), triethylphosphate and DOPOFR polyurethane foam was prepared. Chemical structure of DOPOFR was characterized with FTIR, 1HNMR spectra, and 31PNMR spectra. The thermal stability, flameretardant properties, and mechanical behavior of PUFs with different contents of DOPOFR were investigated by thermogravimetric analysis, limited oxygen index, and universal testing machine. It showed that DOPOFR could form more char when it was lighted and get excellent flame retardancy for PUFs. The 　limited oxygen index value reached 24.7 % with only 20 wt % of DOPOFR. The synergistic effect among EG, triethylphosphate, and DOPOFR could further increase the limited oxygen index to 32 %.

中图分类号:

TQ328. 3

张立强张猛周永红胡立红杨晓慧. 阻燃剂DOPO-FR的合成及阻燃聚氨酯的性能研究 [J]. 中国塑料, 2013, 27(11): 84-88.

阻燃剂DOPO-FR的合成及阻燃聚氨酯的性能研究

Synthesis of DOPO-FR and Performance of Flame Retardant Polyurethane Foams

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价