中国塑料 ›› 2011, Vol. 25 ›› Issue (11): 16-21 .DOI: 10.19491/j.issn.1001-9278.2011.11.004

• 材料与性能 • 上一篇    下一篇

ABS增韧PC/CF复合材料加工流变行为与力学性能

魏立东 徐艺 林润雄 张林   

  1. 中国工程物理研究院激光聚变研究中心;青岛科技大学高分子科学与工程学院
  • 收稿日期:2011-06-22 修回日期:2011-08-01 出版日期:2011-11-26 发布日期:2011-11-26

Processing Rheological and Mechanical Properties of ABS Toughening PC/CF Composites

  

  • Received:2011-06-22 Revised:2011-08-01 Online:2011-11-26 Published:2011-11-26

摘要: 利用微量双螺杆挤出机,通过熔融共混挤出注塑的方法,在PC/CF共混体系中添加ABS对其进行增韧改性,实验对共混体系加工过程中的流变行为进行了分析,分别研究了碳纤维及ABS的含量对复合材料力学性能的影响,并探讨了黏度与力学性能变化的机理,最后通过扫描电子显微镜观测拉伸及冲击破坏的试样断面形态。结果表明,当CF含量为2%时,PC/CF复合材料假塑性最强,熔融状态下易于流动加工,力学性能也最为优异;CF含量不变,当ABS含量为30% ~ 35%时,PC/CF/ABS三元共混物同时具有良好的流动性及力学性能。扫描电镜照片显示,拉伸破坏的主要破坏方式为界面脱胶,而冲击破坏的主要破坏方式为纤维断裂;PC/CF/ABS三元共混物试样断裂面韧性断裂成份要明显多于PC/CF二元共混物,表明复合材料的力学性能得到了改善。

关键词: 聚碳酸酯, 碳纤维, 丙烯腈-丁二烯-苯乙烯共聚物, 增韧

Abstract: In this paper, based on melting experiments of Acrylonitrile-Butadiene-Styrene Copolymer-toughening carbon fiber/polycarbonate composite materials in micro twin-screw extruder, the rheological behavior of PC/CF/ABS blends was studied during melting process, the effects of CFs content and ABS content on mechanical properties of PC/CF/ABS blends and the mechanism of variable viscosity and mechanical properties were studied, the mechanism of the change of viscosity and the mechanical properties were also discussed. The results showed that when CF content was 2%, the minimum of non-Newtonian value was obtained, meanwhile, the mechanical properties and processing properties of composite were outstanding. Above all, when CF content was 2%, ABS content was between 30% ~ 35%, the mechanical properties and good processing properties of the PC/CF/ABS composites were obtained. Scanning electron microscopy analysis showed: the tensile failure of composites was mainly interface degumming, and the impact failure of composites was mainly fiber breakage. Compared with PC/CF composites, the ratio of tough fracture of PC/CF/ABS composites increase, it shows that the mechanical properties of composites improved.

Key words: polycarbonate, carbon fiber, acrylonitrile-butadiene-styrene copolymer, toughening

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