China Plastics ›› 2016, Vol. 30 ›› Issue (05): 13-18 .DOI: 10.19491/j.issn.1001-9278.2016.05.003
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Abstract: The thermal decomposition kinetics and mechanism of polyamide 12(PA12) was investigated by means of TGA at different heating rate in nitrogen atmosphere The thermal decomposition activation energy, thermal decomposition kinetics and model were obtained from Freeman Carroll method, Kissinger method, Ozawa method, Achar and Coats Redfern method The thermal decomposition activation energy and the preexponential constant of PA12 were 246.5 kJ/mol and 1014.71, respectively; the thermal decomposition mechanism of PA12 followed contraction cylinder theorem of which the differential form was f(α)=3(1-α)2/3 and the integral form was G(α)=1-(1-α)1/3.
Key words: polyamide 12, thermal decomposition kinetics, thermal decomposition mechanism
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URL: https://www.plaschina.com.cn/EN/10.19491/j.issn.1001-9278.2016.05.003
https://www.plaschina.com.cn/EN/Y2016/V30/I05/13