Fabrication of Oil Absorption Resin by Irradiation Method and Its Absorption Performance for Typical Organic Chemicals

doi:10.19491/j.issn.1001-9278.2021.01.005

Abstract

Abstract:

An oil absorption resin was synthesized through initiation with a gamma ray using 2-ethylhexyl acrylate as a monomer， divinylbenzene （DVB） as a chemical crosslinker， and cyclohexane as a solvent， and its thermal stability and typical functional groups were analyzed by thermogravimetric analysis and Fourier-infrared spectroscopy. Furthermore， its absorbency performance for some typical organic chemicals such as aliphatic hydrocarbons， aromatic hydrocarbons， ketones， acetates， ethers， halogenated hydrocarbons and fuel oils were investigated through adsorption experiments. The results indicated that the molecular weight and polarity of organic chemicals were important factors for the absorbency performance of this resin. The oil absorption resin presented favorable absorbency to most of the organic chemicals with an absorption rat of 10~30 g/g， and it possessed an amazing absorption rate of 50.48 g/g to chloroform.

Key words: oil absorption resin, γ ray, irradiation polymerization, organic chemical

CLC Number:

TQ 320.9

ZHU Mingxin, LIU Zhiying. Fabrication of Oil Absorption Resin by Irradiation Method and Its Absorption Performance for Typical Organic Chemicals[J]. China Plastics, 2021, 35(1): 25-30.

Figures/Tables 11

Fig.1. Schematic illustration for fabrication of oil absorbency resin

Fig 2. FTIR spectra of oil absorption resin

Fig 3. TG and DTG curves of oil absorption resin

Fig.4. Oil absorbency of the resin to petroleum ether，n?heptane and liquid paraffin vs time

Fig.5. Oil absorbency of the resin to benzene，toluene and xylene against time

Fig.6. Oil absorbency of the resin to acetone，butanone and 2?pentanone against time

Fig.7. Oil absorbency of the resin to ethyl acetate，butyl acetate and isoamyl acetate against time

Fig.8. Oil absorbency of the resin to ethyl ether and tetrahydrofuran against time

Fig.9. Oil absorbency of the resin to dichloromethane and chloroform against time

Fig.10. Oil absorbency of the resin to diesel and kerosene against time

Fig.11. Schematic illustration of absorption mechanism of the resin

References 13

1	ZHU J D，HU J， PENG T P， et al. Superhydrophobic Melamine⁃Formaldehyde Sponge Functionalized by Coupling Agent⁃Isocyanate Siloxane as Efficient Absorbents for Oil and Organic Solvents ［J］. Advanced Materials Interfaces2019， 6（10）： 1900025.
2	LU J W， XU D D， WEI J K， et al. Superoleophilic and Flexible Thermoplastic Polymer Nanofiber Aerogels for Removal of Oils and Organic Solvents［J］. ACS Applied Materials& Interfaces， 2017， 9（30）： 25 533⁃25 541.
3	王洁，商平.有机膨润土改性高吸油树脂的制备与性能研究［J］.中国塑料，2009，23（11）：48⁃52.
	WANG J， SHANG P. Preparation and Properties of Organic Bentonite Compound ModifiedHigh Oil Absorption Resin ［J］. China Plastics， 23（11）：48⁃52.
4	陆平，王晓丽，彭士涛，等.高吸油材料的研究进展［J］.现代化工， 2019，39（4）：22⁃26.
	LU P， WANG X L， PENG S T， et al. Research Progress in Oil⁃absorption Materials ［J］， Modern Chemical Industry，2019，39（4）：22⁃26.
5	耿孝岭，张智嘉，王国军，等. 快速高吸有机溶剂树脂制备及其性能研究［J］.中国塑料，2019，33（12）：1⁃6.
	GENG X L， ZHANG Z J， WANG G J， etal. Preparation and Properties of Organic Solvent⁃absorption Resin with Rapid Rate and High Capacity ［J］. China Plastics， 2019，33（12）：1⁃6.
6	胡静璇，杜姗姗，任秀梅，等.橡胶基丙烯酸酯系高吸油树脂的制备及性能［J］. 高分子材料科学与工程，2016，32（10）：149⁃153+159.
	HU J X， DU S S， REN X M， et al. Preparation and Properties of Rubber Based Acrylic Series High Oil Absorption Resin ［J］. Polymer Materials Science And Engineering， 2016， 32（10）：149⁃153+159.
7	SHAN G R， XU P Y， WENG Z X，et al. Synthesis and Properties of Oil Absorption Resins Filled with Polybutadiene ［J］. Journal of Applied Polymer Science， 2003， 89（12）：3309⁃3314.
8	杨杰，舒武炳，秦卫. 微乳液聚合制备多孔高吸油甲基丙烯酸酯类树脂的研究［J］. 高分子学报， 2010（7）：910⁃917.
	YANG J， SHU W B， QIN W. Preparation of Porous High Oil⁃absorption Methacrylate Resin with Microemulsion Polymerization ［J］. Acta Polymerica Sinica， 2010（7）：910⁃917.
9	ZHOU M H， CHO W J. High Oil⁃absorptive Composites Based on 4⁃tert⁃butylstyrene⁃EPDM⁃divinylbenzene Graft Polymer ［J］. Polymer International， 2001， 50（11）：1 193⁃1 200.
10	武元鹏，杨浩，胡帆，等. P（tBS⁃co⁃MMA）磁性吸油树脂的制备和性能［J］. 高分子材料科学与工程， 2016，32（6）：18⁃21.
	WU Y P， YANG H， HU F， et al. Preparation and Properties of P（tBS⁃co⁃MMA） Magnetic Polymeric Composite Resins ［J］. Polymer Materials Science & Engineering. 2016，32（6）：18⁃21.
11	吴奎，褚效中，周守勇，等. 聚甲基丙烯酸丁酯⁃苯乙烯高吸油树脂的制备及其吸油性能研究［J］. 高校化学工程学报，2013，27（1）：76⁃83.
	WU K， CHU X Z， ZHOU S Y， et al. Preparation of Highly Oil Absorptive Resin Poly （Butyl Methacrylate⁃Styrene） and Its Oil Absorption Performance ［J］. Journal of Chemical Engineering of Chinese Universities， 2013，27（1）：76⁃83.
12	胡婷，姚晓. 丙烯酸丁酯⁃苯乙烯共聚乳液型吸油树脂的合成及性能研究［J］. 化工新型材料， 2011， 39（10）：107⁃109.
	HU T， YAO X. Synthesis and Properties of Oil⁃absorbing Emulsion by Copolymerization of Butyl Acrylate and Styrene ［J］. New Chemical Materials， 2011， 39（10）：107⁃109.
13	徐萍英，单国荣，翁志学，等.吸油树脂中的物理交联［J］，功能材料，2002，6：601⁃604+608.
	XU P Y， SHAN G R， WENG Z X， et al.The Physical Crosslinking in the Oil Absorptions Resin ［J］. Journal of Functional Materials， 2002， 6：601⁃604+608.