中国塑料 ›› 2009, Vol. 23 ›› Issue (04): 24-28 .DOI: 10.19491/j.issn.1001-9278.2009.04.006

• 材料与性能 • 上一篇    下一篇

相对分子质量对PVC/ABS合金结构及性能影响的研究

于杰 贺杰 郭建兵 罗筑 秦舒浩   

  1. 国家复合改性聚合物材料工程技术研究中心
  • 收稿日期:2008-12-02 修回日期:1900-01-01 出版日期:2009-04-26 发布日期:2009-04-26

Study on structure and properties of different molecular weight PVC/ABS alloy

  • Received:2008-12-02 Revised:1900-01-01 Online:2009-04-26 Published:2009-04-26

摘要: 采用锥形双螺杆挤出机制备了不同基体分子量的PVC/ABS合金,采用转矩流变仪、扫描电子显微镜(SEM)研究了PVC分子量对PVC/ABS合金流变行为、相形态及力学性能的影响。结果表明: PVC/ABS合金呈现典型的“海-岛”结构,两者有较好的相容性,随着PVC分子量的增加,ABS相区平均尺寸略有增加且尺寸分布变宽;PVC分子量增大使得PVC/ABS共混物的平衡扭矩明显增大,表观黏度增加;随着ABS含量的增加, 不同PVC分子量的PVC/ABS合金的韧性均得到了大幅的提高, 当ABS含量增加到10 phr以上时,不同PVC分子量的PVC/ABS合金均达到超韧,PVC分子量增大使得PVC/ABS合金的增韧效果更显著。

关键词: PVC, 分子量, 相形态, ABS

Abstract: Use of conical twin-screw extruder mechanism for the preparation of different molecular weight PVC plastic injection-class PVC/ABS alloy,which have high-performance integrated mechanical. Using torque rheometer,scanning electron microscopy (SEM) study on the molecular weight PVC for PVC/ABS alloy rheological behavior, structure and mechanical properties. The results showed that: ABS "particles" in the PVC scattered, dispersed phase size smaller, PVC/ABS alloy showed a typical "sea - island" structure, which has good compatibility, with the increase in molecular weight PVC , ABS with a slight increase in the size of the average district size and wider distribution; PVC molecular weight increases so that the PVC/ABS blends balance significantly increased torque, increased apparent viscosity; with the content of ABS, PVC of different molecular weight PVC/ABS alloy toughness have been a substantial increase, when the ABS content increased to more than 10phr, PVC of different molecular weight PVC/ABS alloy are up to super-tough, PVC increased weight makes PVC/ABS Toughening of the alloy more significant effect.

Key words: PVC, molecular weight, morphology, ABS

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