中国塑料 ›› 2014, Vol. 28 ›› Issue (05): 42-47 .DOI: 10.19491/j.issn.1001-9278.2014.05.008

• 材料与性能 • 上一篇    下一篇

聚对苯二甲酸丙二醇酯/丙烯腈-苯乙烯-丙烯酸酯共聚物共混物的制备与性能

刘迎宾闰明涛1,钟宇2,杨红军   

  1. 1. 河北大学化学与环境科学学院2. 河北大学化学院
  • 收稿日期:2014-01-15 修回日期:2014-02-14 出版日期:2014-05-26 发布日期:2014-05-26

Preparation and Properties of Blends of Poly(trimethylene terephthalate)/Acrylonitrile-styrene-acrylic Copolymer

  • Received:2014-01-15 Revised:2014-02-14 Online:2014-05-26 Published:2014-05-26

摘要: 采用扫描电子显微镜、偏光显微镜、万能材料试验机及毛细管流变仪等对聚对苯二甲酸丙二醇酯/丙烯腈-苯乙烯-丙烯酸酯共聚物(PTT/ASA)共混物的相形态、力学性能、流变性能和热老化性能进行了研究。结果表明,PTT 和ASA具有部分相容性,当ASA含量为50 %时,共混物中形成了双连续相;随着ASA含量的增加,共混物的断面变得更粗糙,断裂方式转变为韧性断裂,ASA的加入明显提高了共混物的缺口冲击强度,但却降低了拉伸强度;共混物熔体为假塑性流体,随着ASA含 量 增 加,熔体表观黏度升高、假塑性越明显,PTT的加工性能得到改善;PTT/ASA比PTT/丙烯腈-丁二烯-苯乙烯(ABS)共混物具有更好的耐热老化性能。

关键词: 聚对苯二甲酸丙二醇酯, 丙烯腈-苯乙烯-丙烯酸酯共聚物, 相形态, 流变学, 热老化

Abstract: Blends of poly(trimethylene terephthalate)/acrylonitrile-styrene-acrylic copolymer were prepared through melt extrusion. The morphology, rheology, thermal aging, and mechanical properties of the blends were investigated using the scanning electrole microscopy, universal material testing machine, and a capillary rheometer. It was found that ASA and PTT were partially miscible in the blends. When ASA content was 50 %, a binary continuous phase formed. The blend’s fracture surface became rough with increasing ASA content. ASA component improved the impact strength but depressed the tensile strength of the blends. The apparent viscosity increased with increasing ASA content and the latter improved the processing property of the blends. The blend’s pseudoplasticity increased with increasing ASA content. Moreover, PTT/ASA blend had better thermal aging resistance than that of PTT/ASA blend.

Key words: poly(trimethylene terephthalate), acrylonitrile-styrene-acrylate copolymer, phase morphology, rheology, thermal aging