中国塑料 ›› 2011, Vol. 25 ›› Issue (08): 48-51 .DOI: 10.19491/j.issn.1001-9278.2011.08.012

• 材料与性能 • 上一篇    下一篇

PTFE乳液制备PTFE/ZrO2微孔膜及性能研究

满瑞 邓新华 孙元 罗衍慧   

  1. 天津工业大学 天津工业大学 天津工业大学 天津工业大学
  • 收稿日期:2011-05-30 修回日期:2011-06-25 出版日期:2011-08-26 发布日期:2011-08-26

Preparation of PTFE/ZrO2 Composite Microporous Membrane by PTFE Resin Emulsion and Investigation on Performance

  

  • Received:2011-05-30 Revised:2011-06-25 Online:2011-08-26 Published:2011-08-26

摘要: 尝试以聚四氟乙烯(PTFE)乳液为原料制备PTFE微孔膜,选定化学稳定性、热稳定性优异的纳米二氧化锆(ZrO2)作为增强剂以提高微孔膜强度,采用电子万能力学试验机测试了样品的力学强度,用单因素法讨论了纳米ZrO2含量、拉伸比例、热处理温度和热处理时间对微孔膜拉伸强度的影响;同时采用低温等离子体处理PTFE/ZrO2复合微孔膜以改善其表面亲水性。结果表明,PTFE/ZrO2复合微孔膜的拉伸强度与纳米ZrO2含量成正比,与拉伸倍数成反比;其拉伸强度随着热处理温度的升高或热处理时间的延长,呈先增大后减小的变化趋势,分别在310 ℃和10 min时出现最大值;低温等离子体处理的最佳时间为30 s。

关键词: 聚四氟乙烯, 纳米二氧化锆, 微孔膜, 低温等离子体

Abstract: This paper used polytetrafluoroethylene (PTFE) emulsion as a matrix phase, micro-nanozirconium dioxide(ZrO2)powder as a reinforcer to prepare. PTFE/ZrO2 composite membranes via mechanical stretch, and the tensile strength of the membranes was tested. Single-factor method to analyze the effect of ZrO2 powder content, draw ratio, heat-treatment temperature, and heat-treatment time on the tensile strength of the composite membrane. PTFE/ZrO2 membranes were post-treated by low-temperature plasma to study the effect of the plasma treatment time and ZrO2 power on the hydrophility of the membranes. It showed that the tensile strength of PTFE/ZrO2 composite membranes increased with increasing ZrO2 content, but decreased with increasing of draw ratio. When heat-treatment temperature was 310 ℃, heat-treatment time was 10 min, the tensile strength gave rise to a maximum. The best post-treated time of low-temperature plasma was 30 s.

Key words: polytetrofluoroethylene(PTFE), nanozirconim dioxide, microporous membrane, low-temperature plasma