中国塑料 ›› 2012, Vol. 26 ›› Issue (05): 94-97 .DOI: 10.19491/j.issn.1001-9278.2012.05.017

• 助剂 • 上一篇    下一篇

硼硅树脂的合成及其对PE-LD/EVA/IFR复合材料阻燃性能和力学性能的影响

王峰 谷晓昱 张胜 陈晓平 陈小随 董明哲   

  1. 北京化工大学碳纤维及功能高分子教育部重点实验室 北京化工大学 碳纤维及功能高分子教育部重点实验室
  • 收稿日期:2011-12-26 修回日期:1900-01-01 出版日期:2012-05-26 发布日期:2012-05-26

Synthesis of Polyborosiloxane and Its Effect on Flame Retardancy and Mechanical Properties of PE-HD/EVA/IFR Composites

WANG Feng GU Xiaoyu ZHANG Sheng CHEN Xiaoping CHEN Xiaosui DONG Mingzhe   

  • Received:2011-12-26 Revised:1900-01-01 Online:2012-05-26 Published:2012-05-26
  • Contact: ZHANG Sheng

摘要: 利用二苯基二甲氧基硅烷和苯基三甲氧基硅烷合成了聚硼硅氧烷树脂,并探索了最佳的合成工艺条件。将聚硼硅氧烷树脂添加到低密度聚乙烯/乙烯醋酸乙烯酯共聚物/膨胀型阻燃剂(PELD/EVA/IFR)复合材料中,以期可以提高膨胀型阻燃剂与聚合物基体的相容性。采用氧指数仪、热重分析仪、力学性能测试等表征手段分析了复合材料的阻燃性能、热性能和力学性能。结果表明,聚硼硅氧烷树脂可提高复合材料的阻燃效果,并且对复合材料的力学性能没有明显的影响。

关键词: 聚硼硅氧烷树脂, 乙烯-醋酸乙烯酯共聚物, 聚乙烯, 膨胀型阻燃剂

Abstract: Polyborosiloxane resin was synthesized from diphenyldimethoxysilane and phenyltrimethoxysilane through hydrolysis and condensation, and then was blended with low density polyethylene/ethylene vinyl acetate coplymer/intumescent flame retardants (PELD/EVA/IFR) composites to improve the compatibility between IFR and polymer. The flammability and the thermal behavior of the composites were investigated using limiting oxygen index and thermogravimetric analysis. It showed that a better flame retardancy was achieved by the addition of the polyborosiloxane resin with minimal negative effects in the mechanical properties.

Key words: polyborosiloxane resin, ethylene vinyl acetate copolymer, low density polyethylene, intumescent flame retardant