中国塑料 ›› 2013, Vol. 27 ›› Issue (02): 60-64.DOI: 10.19491/j.issn.1001-9278.2013.02.012

• 加工与应用 • 上一篇    下一篇

微胶囊法制备高效缓释型芳香塑料

储鸿 俞佳德 倪忠斌 陈明清   

  1. 江南大学 化学与材料工程学院 江南大学
  • 收稿日期:2012-10-31 修回日期:1900-01-01 出版日期:2013-02-26 发布日期:2013-02-26

Preparation of Efficient Prolongreleased Aromatic Plastics with Fragrance Microcapsule

CHU Hong   

  • Received:2012-10-31 Revised:1900-01-01 Online:2013-02-26 Published:2013-02-26

摘要: 以脲醛树脂为壁材,OP10为乳化剂,1∶50盐酸作催化剂,用原位聚合法制备得到包覆良好、球体形态且粒径分布均匀的流动性固体香精微胶囊。采用高微量热天平仪、扫描电子显微镜、光学显微镜研究了固体香精微胶囊的包埋率、胶囊的形态和保香期。结果表明,香精的包埋率达32%,该微胶囊热稳定性良好且具有较好的缓释性能。由此制备得到的含香塑料不变色,香气稳定、强度大,香精的挥发动力学预测该塑料的保香期大于1年;加工过程中,香精的挥发损失率在10 %以下。

关键词: 香精微胶囊, 缓释, 芳香塑料, 保香期

Abstract: Uniform solid fragrance spheric microcapsules with satisfied fluidity were prepared via insitu polymerization using ureaformaldehyde resin as a wall material in the presence of OP10 and hydrochloric acid (1∶50) as emulsifier and catalyst. Embedding rate, morphology, and fragrance longevity were studied using high precision thermal balance, scanning electron microscope, and optical microscope. The embedding rate reached 32 %. The asprepared microcapsules performed thermo stability and controlledrelease behavior. The fragranced plastics prepared with such microcapsules was proved to be scented stably and strongly with its longevity above 1 year. The weight loss of fragrance during the process was less than 10 %.

Key words: fragrance microcapsule, controlledrelease, fragranced plastics, longevity of olfactive perception