中国塑料 ›› 2015, Vol. 29 ›› Issue (11): 1-6 .DOI: 10.19491/j.issn.1001-9278.2015.11.001

• 综述 •    下一篇

四唑基聚合物的研究进展

王晓君1,刘吉平1,赵伟2,毕晓露2,王栋2   

  1. 1. 北京理工大学2. 北京理工大学材料学院
  • 收稿日期:2015-06-02 修回日期:2015-11-04 出版日期:2015-11-26 发布日期:2015-11-26

Research Progress on Tetrazolyl Polymer

  • Received:2015-06-02 Revised:2015-11-04 Online:2015-11-26 Published:2015-11-26

摘要: 综述了四唑基聚合物的合成方法,包括环加成反应、自由基聚合反应、官能团反应。介绍了四唑基聚合物在含能材料和质子交换膜材料方面的应用,四唑基聚合物用于制备含能材料具有能量高、感度低的优点,而作为质子交换膜材料,不但具有基本的导电性能,还能在高温及无水情况下的应用。

关键词: 四唑基聚合物, 环加成, 自由基聚合, 黏合剂, 质子交换膜

Abstract: This article mainly introduced the synthesis methods of tetrazolyl polymer,including cycloaddition reaction method,free radical polymerization, and functional group reaction method. The application of tetrazolyl polymer in energetic material and membrane material was introduced. Tetrazolyl polymerhas advantage of high energy and low sensitivity in energetic material. Tetrazolyl polymer not only has conductivity but also can be applied in the environment at high temperature and without water.

Key words: Tetrazolyl polymer, Cycloaddition, Free radical polymerization, Binding agent, Proton exchange membrane