中国塑料 ›› 2019, Vol. 33 ›› Issue (5): 30-36.DOI: 10.19491/j.issn.1001-9278.2019.05.006

• 材料与性能 • 上一篇    下一篇

阻燃聚氨酯弹性体复合材料的制备及性能研究

刘新亮1,王涛2,刘纯林1,张浩2,刘秀玉1,唐刚1   

  1. 1. 安徽工业大学建筑工程学院
    2. 安徽工业大学 建筑工程学院
  • 收稿日期:2018-12-17 修回日期:2019-01-24 出版日期:2019-05-26 发布日期:2019-06-26
  • 基金资助:
    中国博士后科学基金资助项目;中国博士后科学基金资助项目;大学生创新创业训练计划项目

Preparation and Properties of Flame-retardant Thermoplastic Polyurethane Composites

  • Received:2018-12-17 Revised:2019-01-24 Online:2019-05-26 Published:2019-06-26
  • Contact: Gang TANG E-mail:gangtang@mail.ustc.edu.cn

摘要: 以次磷酸铝(AHP)和三聚氰胺氰脲酸盐(MCA)为阻燃剂,采用熔融共混法制备了一系列阻燃聚氨酯弹性体复合材料(FR-TPU),采用热失重分析、极限氧指数、UL 94 垂直燃烧测试、锥形量热测试、力学性能测试、扫描电子显微镜研究了FR-TPU复合材料的热稳定性、阻燃性能、燃烧性能、力学性能和炭渣形貌。结果表明,AHP与MCA复配可明显提高FR-TPU复合材料的热稳定性、成炭率和阻燃性能;TPU/AHP-MCA20的极限氧指数为30.5 %,并达到UL 94 V-0级,热释放速率峰值(PHRR)和总热释放量(THR)分别下降至436 kW/m2和55.5 MJ/m2,拉伸强度和断裂伸长率分别为25.45 MPa和588.3 %;AHP与MCA复配可明显提高TPU/AHP-MCA20炭渣的致密性,从而有效抑制燃烧区域物质及能量交换,提高复合材料的火灾安全性。

Abstract: Aluminum hypophosphite (AHP) and melamine cyanurate (MCA) were adopted as flame retardants to prepare a series of flame retardant thermoplastic polyurethane elastomer composites (FR-TPU) by a melt blending method. The thermal stability, flame retardant performance, combustion properties, mechanical properties and char morphology of the resulting FR-TPU were investigated by means of thermogravimetric analysis, limiting oxygen index (LOI) test, UL 94 vertical burning experiment, cone calorimetry, mechanical measurements and scanning electron microscopy. The results indicated that the combination of AHP and MCA could enhance the flame retardancy of TPU, and the FR-TPU containing 20 wt.% of AHP-MCA achieved a LOI of 30.5 vol.% as well as a UL 94 V-0 classification in the vertical burning test, and its peak heat release rate and total heat release were reduced to 436 kW/m2 and 55.5 MJ/m2, respectively. Moreover, the FR-TPU presented the tensile strength of 25.45 MPa and elongation at break of 588.3 %. Morphological observation demonstrated that the combination of AHP and MCA significantly enhanced the compactness of residual char for FR-TPU. In this case, the compact char layer could effectively inhibit the mass and heat transfer of combustion area, thus enhancing the fire safety of the composites.