造纸黑液木质素作为EPDM橡胶偶联剂的研究

doi:10.19491/j.issn.1001-9278.2019.11.015

中国塑料 ›› 2019, Vol. 33 ›› Issue (11): 78-82.DOI: 10.19491/j.issn.1001-9278.2019.11.015

造纸黑液木质素作为EPDM橡胶偶联剂的研究

严光宇¹,徐鸽²

1. 常州信息职业技术学院 2. 常州大学石油化工学院

收稿日期:2019-06-27 修回日期:2019-07-28 出版日期:2019-11-26 发布日期:2019-12-27

Investigation on Lignins from Pulping Black Liquor as Coupling Agent for EPDM

YAN Guangyu¹, XU Ge²

1.Changzhou College of Information Technology，Changzhou 213164，China;
2.School of Petrochemical Engineering,Changzhou University，Changzhou 213164,China)

Received:2019-06-27 Revised:2019-07-28 Online:2019-11-26 Published:2019-12-27

摘要/Abstract

摘要： 采用硝酸和硫酸由碱法造纸黑液中酸析得到2种木质素，对其进行了粒径分布分析。研究了分别添加这2种木质素和硅烷偶联剂对三元乙丙橡胶（EPDM）性能的影响。结果表明，2种木质素具有较小的中位径和较大的比表面积，加入EPDM橡胶中，比硅烷偶联剂更能改善其力学性能；当加入1.5 %（基于100 g橡胶）硝酸盐木质素时，EPDM橡胶的拉伸强度、断裂伸长率和肖A硬度分别提高了21.42 %、 22.55 % 和8；傅里叶红外光谱分析（FTIR）和扫描电子显微镜（SEM）结果证实木质素对橡胶有补强作用；而热失重（TG）结果说明木质素和硅烷偶联剂一样均能提高EPDM橡胶的热稳定性；木质素替代硅烷偶联剂用于EPDM橡胶，可改善其性能，降低生产成本，有较好的应用前景。

关键词: 三元乙丙橡胶, 造纸黑液木质素, 硅烷偶联剂, 表征

Abstract: Two types of lignins were obtained from alkaline pulping black liquors by acidulation using nitric acid and sulphuric acid, and their particle-size distributions were analyzed. A comparative investigation was conducted for the properties of ethylene-propylene-diene-monomer (EPDM) rubbers with the two types of lignins and silane-coupling agent. The results indicated that the two types of lignins exhitibted a smaller value of D50 and a bigger specific surface area. The incorporation of lignin-coupling agents improved the mechanical performances of EPDM rubber more significantly than the silane-coupling agent. The tensile strength, elongation at break and hardness of EPDM rubbers increased by 21.42 %, 22.55 % and 8 degree with the addition of 1.5 phr nitrate lignin (based 100 g rubber). The Fourier-transform infrared spectroscopy (FTIR) analysis and scanning electron microscopic (SEM) observation indicated that the lignins played a role in the reinforcement of EPDM rubber. Thermogravimetric analysis revealed that the lignins and silane-coupling agents improved the thermal stability of EPDM rubbers. The lignins could be used to replace the silane-coupling agent for modification of EPDM rubbers in a cost-effective way and therefore exhibited good application potential.

Key words: ethylene-propylene-diene-monomer rubber, lignins from pulping black liquor, silane coupling agent, characterization

中图分类号:

TQ330.387

严光宇徐鸽. 造纸黑液木质素作为EPDM橡胶偶联剂的研究[J]. 中国塑料, 2019, 33(11): 78-82.

YAN Guangyu, XU Ge. Investigation on Lignins from Pulping Black Liquor as Coupling Agent for EPDM[J]. China Plastics, 2019, 33(11): 78-82.

参考文献

[1]Norgren M，Edlund H.Lignin：recent advances and emerging applications[J].Curr Opin colloid Interface Sci, 2014, 19(5):409-416 [2]Naron D R，Coliard F X，Tyhodal，et al..Characterisation of lignins from different sources by appropriate analytical methods: introducing thermogravimetric analysis—thermal desorption-gas chromatography-mass spectroscopy[J].Ind crops Prod, 2017, 101(/):61-74 [3]耿莉莉，张宏喜，周婷婷，等.木质素结构及其催化转化方法的研究进展[J].广州化工, 2016, 44(20):4-6 [4] 徐鸽，张静.木质素作为橡胶偶联剂、补强剂的研究[J].河南化工, 2000, /(7):16-17 [5]何益艳，张吉才，杜仕国.偶联剂在橡胶中的应用[J].弹性体, 2002, 12(4):55-59 [6]苏鹏，邹晓轩，杨家富，等.马来酸酐接枝三元乙丙橡胶共聚物增容／共混物的研究[J].中国塑料, 2016, 30(5):50-54 [7] Yu T, Lin J, Xu J, et al.Novel polyacrylonitrile/Na-MMT/silica nanocomposite: co-incorporation of two different form nano materials into polymer matrix[J].Compos Sci Technol, 2007, 67(15-16):3219-3225 [8] 翁诗甫.傅里叶变换红外光谱分析（第二版）[M]. 北京：化学工业出版社，2010：291-362. [9]武晶，韩文霞.用红外光谱法鉴别聚合物[J].橡胶参考资料, 2005, 35(1):38-44 [10] 马礼敦.高等结构分析（第一版）[M]. 上海：复旦大学出版社，2002：161-165. [11] Ciesielczyk F, Klapiszewski ?, Szwarc-Rzepka K, et al.A novel method of combination of Kraft lignin with synthetic mineral support[J].Adv Powder Technol, 2013, 25(2):695-703 [12] Morandim-Giannetti A A, Agnelli J A M, Lancas B Z, et al.Lignin as additive in polypropylene/coir composites: Thermal, mechanical and morphological properties[J].Carbohydr Polym, 2012, 87(4):2563-2568

[1]	刘强, 卢亚红, 吴慧, 马瑜浩, 张宇鹏, 孙文潇, 张宏. 聚乙烯塑料的微生物降解[J]. 中国塑料, 2022, 36(3): 120-126.
[2]	杨小龙, 李永青, 闫晓堃, 陈文静, 马秀清. 聚合物/石墨烯阻气型复合材料的研究进展[J]. 中国塑料, 2021, 35(12): 145-153.
[3]	罗通通, 孙玲. 偶联剂对PLA/PBAT/WF复合材料3D打印性能的影响[J]. 中国塑料, 2020, 34(11): 66-72.
[4]	张龙贵, 李娟, 计文希. 支化聚酰胺6的研究进展[J]. 中国塑料, 2017, 31(08): 1-6 .
[5]	谷亚新, 刘根华, 王洪梅, 王晴, 桂建锋. 氧化铝对耐热聚乙烯复合材料性能的影响[J]. 中国塑料, 2017, 31(07): 48-52 .
[6]	刘永涛, 廖辉伟, 邓秋林, 张亚莉, 郭文杰, 王少波, 曾卓. 聚苯胺/改性胶粉导电材料的制备及其性能研究[J]. 中国塑料, 2016, 30(02): 32-38 .
[7]	霍朝沛, 任冬云. 基于香农熵的超细粉体填料混合均匀度的评价研究[J]. 中国塑料, 2015, 29(09): 12-16 .
[8]	杨学莉, 于磊, 刘文广, 张秀成. 偶联剂对PBS/碳酸钙晶须复合材料力学性能与热稳定性的影响[J]. 中国塑料, 2015, 29(06): 28-33.
[9]	刘继云杨学莉刘莹莹魏哲梅张秀成. 表面改性核桃壳对聚乳酸/核桃壳粉体复合材料性能的影响[J]. 中国塑料, 2014, 28(03): 40-45 .
[10]	沈志伟朱志开车波李锦春陈强. 氧化石墨改性酚醛泡沫材料的制备及其表征[J]. 中国塑料, 2013, 27(05): 34-38 .
[11]	孙强黄关葆. 聚丙烯/无机粉体/异形纤维复合材料的制备[J]. 中国塑料, 2012, 26(04): 54-60 .
[12]	盛雨峰温变英胡笑千. 硅烷偶联剂对聚乳酸/甘蔗渣复合材料力学性能的影响[J]. 中国塑料, 2012, 26(01): 87-92 .
[13]	郭甜甜丁雪佳张雨周克斌. 滑石粉对聚丙烯微观形态和性能影响[J]. 中国塑料, 2011, 25(12): 39-42.
[14]	汪凌甄卫军李亚瑜刘月娥庞桂林. PLA/HTCC-MMT插层复合材料的绿色合成、表征及热降解动力学分析[J]. 中国塑料, 2011, 25(06): 42-48 .
[15]	陈睿超孙辉许国志. PEEK的表面改性和表征[J]. 中国塑料, 2011, 25(05): 17-23 .

造纸黑液木质素作为EPDM橡胶偶联剂的研究

Investigation on Lignins from Pulping Black Liquor as Coupling Agent for EPDM

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价