中国塑料 ›› 2012, Vol. 26 ›› Issue (04): 54-60 .DOI: 10.19491/j.issn.1001-9278.2012.04.011

• 材料与性能 • 上一篇    下一篇

聚丙烯/无机粉体/异形纤维复合材料的制备

孙强 黄关葆   

  1. 北京服装学院 北京服装学院
  • 收稿日期:2011-11-23 修回日期:1900-01-01 出版日期:2012-04-26 发布日期:2012-04-26

Preparation of Polypropylene/Inorganic/Profiled Fibers Composites

SUN Qiang   

  • Received:2011-11-23 Revised:1900-01-01 Online:2012-04-26 Published:2012-04-26

摘要: 以聚丙烯为聚合物基体,以纳米碳酸钙为无机组分,采用聚对苯二甲酸乙二醇酯(PET)纤维,纤维截面形状分别为圆形、扁平形和三角形,通过熔融共混的方法制备了聚丙烯/纳米碳酸钙/异形纤维复合材料,并采用不同的改性剂对纳米碳酸钙进行表面改性,通过扫描电子显微镜观察了纳米碳酸钙的分散情况,重点分析了聚丙烯/纳米碳酸钙/异形纤维复合材料的结构与性能的关系。结果表明,硅烷偶联剂对碳酸钙表面有机化处理的效果好于硬脂酸;纤维截面形状不同对复合材料的增强效果也不同,其中比表面积最大的三角形纤维增强效果最佳;当纳米碳酸钙的含量为3 %(质量分数,下同)(2 %硅烷偶联剂处理)、三角形PET纤维的长径比为80、含量为2 %(体积分数,下同)(4 %硅烷偶联剂处理)时,制得的聚丙烯/纳米碳酸钙/异形纤维复合材料的屈服强度比纯聚丙烯提高近21 %,弹性模量提高了约82 %。

关键词: 纳米碳酸钙, 异形纤维, 复合材料, 聚丙烯, 硅烷偶联剂, 聚对苯二甲酸乙二醇酯, 力学性能

Abstract: Polypropylene (PP)/nano-CaCO3/profiled fibers composites were prepared via melt blending. The profiled fibers had cylindrical, flat, or triangular cross-sections. The structure of untreated and treated CaCO3 was investigated and the dispersion condition was observed by means of SEM. It showed that silane coupling agent was better than stearic acid. Fibers with different cross-sections have different influence on the mechanical properties. The composite containing triangular fiber with the largest surface area was much better than others. When the mass fraction of nano-CaCO3 was 3 % (silane coupling agent was 2 %) and the volume fraction of triangular fibers was 2 % (coupling agent was 4 %),length/diameter(L/D) was 80, the yield strength and elastic modulus of the composites were increased by 21 % and 82 %, respectively.

Key words: calcium carbonate, profiled fiber, composite, polypropylene, coupling agent, polyethylene terephthalate, mechanical property

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