中国塑料 ›› 2007, Vol. 21 ›› Issue (2): 73-76.

• 助剂 • 上一篇    下一篇

(PE-HD/SEBS ) -g-MAH对PE-HD/木粉复合材料增容的研究

石恒冲,李斌*   

  1. 东北林业大学理学院阻燃材料分子设计与制备黑龙江省重点实验室,黑龙江哈尔滨150040
  • 出版日期:2007-02-26 发布日期:2021-03-19
  • 基金资助:
    国家自然科学基金项目((3017075)、黑龙江省杰出青年科学基金项目(JC04-06)

Effect of(PE-HD/SEBS)-g-MAH on the Compatibility of PE-HD/Wood Flour Composites

SHI Heng-chong,LI Bin*   

  1. Heilongjiang Key Laboratory of Molecular Design and Preparation of Flame Retarded Materials, College of Science,Northeast Forestry University, Harbin 150040, China
  • Online:2007-02-26 Published:2021-03-19

摘要: 采用转矩流变仪制备出马来酸醉(MAH)接枝PE-HD/氢化(苯乙烯一丁二烯一苯乙烯)共聚物(SEBS)(PE-HD/SEBS)-g-MAH作为PE-HD/混物木粉复合材料的界面相容剂,并研究了制备过程中转矩的变化,结果表明,体系的转矩随着MAH和引发剂过氧化二异丙苯含量的增加而增加,苯乙烯促进了MAH和PE-HD/SEBS的反应;通过傅里叶红外分析证实了MAH接枝到聚合物上。(PE-I-1D/SEBS) -g-MAH}能明显地提高PE-HD/木粉复合材料的力学性能,当其添加量为2%(质量分数,下同)时复合材料的拉伸强度、弯曲强度和冲击强度分别增加了157 % ,146%和145%扫描电镜也能观察到加人相容剂的复合材料界面粘接非常好,进一步证实了(PE-HD/SEBS)-g-MAH提高了复合材料的界面相容性。

关键词: 高密度聚乙烯, 马来酸配, 接技, 氢化(苯乙烯一丁二烯一苯乙烯)共聚物, 界面相容剂, 木粉

Abstract: (PE-HD/SEBS)-g-MAH was prepared by means of a torque rheometer and was employed as a compatibilizer in PE-HD/wood flour composites. FT-IR confirmed that malefic anhydride ( MAH) was grafted onto PE-HD/SEBS. During the reaction, the torque of the rheometer increased with increasing content of malefic anhydride and dicumyl peroxide. Styrene could promote the rate of reaction between MAH and PE-HD/SEBS. The mechanical properties of PE-HD/wood flour composites were obviously enhanced with (PE-HD/SEBS)-g-MAH.When the content of (PE-HD/SEBS)-g-MAH was 2 wt%,tensile and flexural strengths of the composites reached 25 .9 MPa and 34 .8 MPa, respectively. The notched Izod impact strength reached 5 .081}J /m'`.SEM showed that (PE-HD/SEES)-g-MAH obviously improved the compatibility of PE-HD/wood flour composites.

Key words: high density polyethylene,  , malefic anhydride,  , graft, hydrogenated(styrene-butylene-styrene) terblock polymer, interface compatibilizer, wood flour

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